Gas Phase Coordination Chemistry

Author(s):  
M.T. Rodgers ◽  
P.B. Armentrout
2019 ◽  
Vol 58 (9) ◽  
pp. 6388-6398 ◽  
Author(s):  
Onyekachi Raymond ◽  
Penelope J. Brothers ◽  
Magnus R. Buchner ◽  
Joseph R. Lane ◽  
Matthias Müller ◽  
...  

ChemInform ◽  
2004 ◽  
Vol 35 (48) ◽  
Author(s):  
M. T. Rodgers ◽  
P. B. Armentrout

1979 ◽  
Vol 101 (23) ◽  
pp. 7127-7129 ◽  
Author(s):  
R. C. Burnier ◽  
T. J. Carlin ◽  
W. D. Reents ◽  
R. B. Cody ◽  
R. K. Lengel ◽  
...  

2011 ◽  
Vol 22 (11) ◽  
pp. 2042-2048 ◽  
Author(s):  
Philip X. Rutkowski ◽  
Daniel Rios ◽  
John K. Gibson ◽  
Michael J. Van Stipdonk

2010 ◽  
Vol 65 (3) ◽  
pp. 231-s261 ◽  
Author(s):  
Ralph Puchta ◽  
Andreas Scheurer

Based on density functional calculations (RB3LYP/LANL2DZp) the bicyclic metallocryptand [Pd3(L2)2] [(L2)3−: 1,1´ ,1´´-nitrilotris(5,5-dimethylhexane-2,4-dione trianion)] shows the same high gas-phase basicity (−257.1 kcal mol−1) as Lehn’s [2.2.2] cryptand (−254.4 kcal mol−1). This illustrates that the concept of metallotopomers adopted by Saalfrank et al. can be applied to design proton sponges as well as proton cryptands by metallosupramolecular coordination chemistry. The slightly higher gas-phase proton affinity of [Pd3(L2)2] compared to [2.2.2] can be attributed to the smaller cavity in the metallotopomer.


2011 ◽  
Vol 50 (11) ◽  
pp. 4781-4790 ◽  
Author(s):  
Daniel Rios ◽  
Philip X Rutkowski ◽  
Michael J. Van Stipdonk ◽  
John K. Gibson

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