Hildebrand's Theory in the Light of all Gas Solubility Data

1980 ◽  
pp. 250-274
Author(s):  
WILLIAM GERRARD
1988 ◽  
Vol 42 ◽  
pp. 185-194
Author(s):  
Maria Molnar-Jobbagy ◽  
Jürgen Rarey-Nies ◽  
Jürgen Gmehling

2003 ◽  
Vol 42 (16) ◽  
pp. 3851-3856 ◽  
Author(s):  
Jörn Kiepe ◽  
Sven Horstmann ◽  
Kai Fischer ◽  
Jürgen Gmehling

2005 ◽  
Vol 77 (3) ◽  
pp. 593-603 ◽  
Author(s):  
Séverine A. E. Boyer ◽  
Jean-Pierre E. Grolier

The newly developed VW-pVT technique for simultaneously measuring the solubility of a gas in a polymer and the concomitant change of volume of the polymer has been used to estimate the solubilities of N2, CO2, and two hydrofluorocarbons, HFC-134a and HFC-152a, in polystyrene (PS). In conjunction with these solubility data, Chow’s model has been used to calculate the change of the glass-transition temperature of the polymer resulting from gas sorption. The performance of this model for predicting the glass-transition temperature shift is then discussed.


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