Energy Analysis of HFC-152a, HFO-1234yf and HFC/HFO Mixtures as a Direct Substitute to HFC-134a in a Domestic Refrigerator

The Kyoto protocol emphasized the need of replacement of HFC refrigerant due to their high GWP values that causes pollution in the environment. So in this paper the refrigerants R1234yf, R152a and HFOs/HFCs mixtures of R134a/R152a/R1234yf such as ARM42 (in the ratio of 8.5/14 /77.5 by mass), ARM42a (in the ratio of 7/11/82 by mass) with a view of replacement of the refrigerant HFC-134a in a domestic refrigerator were analyzed theoretically. Volumetric cooling capacity, compressor discharge temperature, coefficient of performance, compressor energy consumption and refrigeration capacity are the main parameters to estimate the performance of the refrigerator. The results are revealed that HFC-152a had gave a superior performance as compared to HFC-134a in terms of COP and equal cooling and volumetric cooling capacities. However, the refrigerant HFC-152a was flammable and runs with high compressor outlet temperature which may restrict its usage. The HFO refrigerant R1234yf showed an almost equal volumetric cooling capacity, compressor energy consumption, refrigerating effect and COP when compared with HFC-134a. Among the refrigerants ARM42 and ARM42a, the refrigerant ARM42a was selected as a good alternative for HFC-134a because the Volumetric cooling capacity and COP of ARM42a were almost equal to HFC-134a. Therefore ARM42a had better choice of direct substitute to HFC-134a in a domestic refrigerator when the corresponding safety requirements are adopted. So on overall comparison of every property of refrigerants we can conclude that R1234yf can be treated as best alternative to HFC-134a in a domestic refrigerator.

Effect of Hydrofluorocarbons and Hydrofluoroolefins in a Household Refrigerator as a Substitute for R134a

Now a days R134a can be used in domestic refrigerators and in air conditioning of automobiles. As per Kyoto protocol the usage of R134a is restricted due to their higher GWP value. The GWP value of this refrigerant is around 1430. So in this article, thermodynamic analysis of HFC-152a, HFO refrigerants-1234ze(E) and 1234yf was done in a household refrigeration system as direct substitute to HFC-134a.The performance of the household refrigerator was compared in terms of outlet temperature of the compressor, volumetric cooling capacity (VCC), refrigeration effect, work done by the compressor and coefficient of performance (COP). The entire analysis is carried out at various operating conditions of condenser and evaporator temperatures i.e. condensation temperature of 25°C,35°C & 45°C and evaporating temperatures ranging between −20°C to 10°C.From the theoretical results, it can be concluded that R1234yf can be used as a direct substitute to R134a.

Performance Comparison of a Low GWP Refrigerants as Alternatives to R134a in a Refrigerator with and without Liquid-Suction Heat Exchanger

The usage of refrigerators and air conditioners are more prevalent in a domestic environment now-a-days. Improving the efficiency of these devices can be considered as an important step to reduce their energy consumption. Currently, in India, most refrigerators work with HFC-134a as a refrigerant. The GWP value of HFC-134a is around 1430.Therefore, there is a greater demand to replace HFCs with low GWP refrigerants. In this document, the comparison of the performance of a refrigerator without fluid intake heat exchanger (LSHX) with low GWP refrigerants and the results are compared with HFC-134a performed. The low GWP refrigerants used in the test are: hydrocarbon-propane (R290) and isobutane (R600a), the pure hydrocarbons are HFC-134a and HFC-152a and the refrigerants are hydrofluoroolefins 1234yf and 1234ze (E). All have been tested without making changes in the system. The entire examination was carried out in the same system under the same working conditions.

Rational design of MgF2 catalysts with long-term stability for the dehydrofluorination of 1,1-difluoroethane (HFC-152a)

In this study, sol–gel, precipitation and hard-template methods were applied to synthesize MgF2 catalysts with improved stability towards dehydrofluorination of hydrofluorocarbons and MgF2-T catalysts demonstrated superior long-term stability.

Abundance and sources of atmospheric halocarbons in the Eastern Mediterranean

A wide range of anthropogenic halocarbons is released to the atmosphere, contributing to stratospheric ozone depletion and global warming. Using measurements of atmospheric abundances for the estimation of halocarbon emissions on the global and regional scale has become an important top-down tool for emission validation in the recent past, but many populated and developing areas of the world are only poorly covered by the existing atmospheric halocarbon measurement network. Here we present 6 months of continuous halocarbon observations from Finokalia on the island of Crete in the Eastern Mediterranean. The gases measured are the hydrofluorocarbons (HFCs), HFC-134a (CH2FCF3), HFC-125 (CHF2CF3), HFC-152a (CH3CHF2) and HFC-143a (CH3CF3) and the hydrochlorofluorocarbons (HCFCs), HCFC-22 (CHClF2) and HCFC-142b (CH3CClF2). The Eastern Mediterranean is home to 250 million inhabitants, consisting of a number of developed and developing countries, for which different emission regulations exist under the Kyoto and Montreal protocols. Regional emissions of halocarbons were estimated with Lagrangian atmospheric transport simulations and a Bayesian inverse modeling system, using measurements at Finokalia in conjunction with those from Advanced Global Atmospheric Gases Experiment (AGAGE) sites at Mace Head (Ireland), Jungfraujoch (Switzerland) and Monte Cimone (Italy). Measured peak mole fractions at Finokalia showed generally smaller amplitudes for HFCs than at the European AGAGE sites except for periodic peaks of HFC-152a, indicating strong upwind sources. Higher peak mole fractions were observed for HCFCs, suggesting continued emissions from nearby developing regions such as Egypt and the Middle East. For 2013, the Eastern Mediterranean inverse emission estimates for the four analyzed HFCs and the two HCFCs were 13.9 (11.3–19.3) and 9.5 (6.8–15.1) Tg CO2eq yr−1, respectively. These emissions contributed 16.8 % (13.6–23.3 %) and 53.2 % (38.1–84.2 %) to the total inversion domain, which covers the Eastern Mediterranean as well as central and western Europe. Greek bottom-up HFC emissions reported to the UNFCCC were higher than our top-down estimates, whereas for Turkey our estimates agreed with UNFCCC-reported values for HFC-125 and HFC-143a, but were much and slightly smaller for HFC-134a and HFC-152a, respectively. Sensitivity estimates suggest an improvement of the a posteriori emission estimates, i.e., a reduction of the uncertainties by 40–80 % in the entire inversion domain, compared to an inversion using only the existing central European AGAGE observations.

Abundance and Sources of Atmospheric Halocarbons in the Eastern Mediterranean

A wide range of anthropogenic halocarbons is released to the atmosphere, contributing to stratospheric ozone depletion and global warming. Using measurements of atmospheric abundances for the estimation of halocarbon emissions on the global and regional scale has become an important top-down tool for emission validation in the recent past, but many populated and developing areas of the world are only poorly covered by the existing atmospheric halocarbon measurement network. Here we present six months of continuous halocarbon observations from Finokalia on the island of Crete in the Eastern Mediterranean. The gases measured are the hydrofluorocarbons (HFCs), HFC-134a (CH2FCF3), HFC-125 (CHF2CF3), HFC-152a (CH3CHF2) and HFC-143a (CH3CF3), and the hydrochlorofluorocarbons (HCFCs), HCFC-22 (CHClF2) and HCFC-142b (CH3CClF2). The Eastern Mediterranean is home to 250 million inhabitants, consisting of a number of developed and developing countries, for which different emission regulations exist under the Kyoto and Montreal Protocols. Regional emissions of halocarbons were estimated with Lagrangian atmospheric transport simulations and a Bayesian inverse modelling system, using measurements at Finokalia in conjunction with those from Advanced Global Atmospheric Gases Experiment (AGAGE) sites at Mace Head (Ireland), Jungfraujoch (Switzerland) and Monte Cimone (Italy). Measured peak mole fractions at Finokalia showed generally smaller amplitudes for HFCs than at the European AGAGE sites, except periodic peaks of HFC-152a, indicating strong upwind sources. Higher peak mole fractions were observed for HCFCs, suggesting continued emissions from nearby developing regions such as Egypt and the Middle East. For 2013, the Eastern Mediterranean inverse emission estimates for the four analysed HFCs and the two HCFCs were 14.7 (6.7–23.3) Tg CO2eq yr-1 and 9.7 (4.3–15.7) Tg CO2eq yr-1, respectively. These emissions contributed 17.3 % (7.9–27.4 %) and 53 % (23.5–86%) to the total inversion domain, which covers the Eastern Mediterranean as well as Central and Western Europe. Greek bottom-up HFC emissions reported to the UNFCCC were much smaller than our top-down estimates, whereas for Turkey our estimates agreed with UNFCCC-reported values for HFC-125 and HFC-143a, but were much and slightly smaller for HFC-134a and HFC-152a, respectively. Sensitivity estimates suggest an improvement of the a posteriori emission estimates, i.e. a reduction of the uncertainties by 40–80 %, compared to an inversion using only the existing Central European AGAGE observations.