A Systematic Approach to the Synthesis, Thermal Stability and Hydrogen Storage Properties of Rare-Earth Borohydrides

Author(s):  
Fabiana C. Gennari ◽  
Julio J. Andrade-Gamboa
Energies ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 8163
Author(s):  
Toyoto Sato ◽  
Shin-ichi Orimo

REMgNi4-based alloys, RE(2−x)MgxNi4 (RE: rare-earth metals; 0 < x < 2), with a AuBe5-type crystal structure, exhibit reversible hydrogen absorption and desorption reactions, which are known as hydrogen storage properties. These reactions involve formation of three hydride phases. The hydride formation pressures and hydrogen storage capacities are related to the radii of the RE(2−x)MgxNi4, which in turn are dependent on the radii and compositional ratios of the RE and Mg atoms. The crystal structures formed during hydrogen absorption reactions are the key to understanding the hydrogen storage properties of RE(2−x)MgxNi4. Therefore, in this review, we provide an overview of the crystal structures in the hydrogen absorption reactions focusing on RE(2−x)MgxNi4.


2014 ◽  
Vol 39 (17) ◽  
pp. 9267-9275 ◽  
Author(s):  
Huai-gang Zhang ◽  
Peng Lv ◽  
Zhong-min Wang ◽  
Huai-ying Zhou ◽  
Jian-qiu Deng ◽  
...  

2013 ◽  
Vol 563 ◽  
pp. 1-5 ◽  
Author(s):  
He-xin Chen ◽  
Zhong-min Wang ◽  
Huai-ying Zhou ◽  
Chen-yuan Ni ◽  
Jian-qiu Deng ◽  
...  

2015 ◽  
Vol 645 ◽  
pp. S155-S159 ◽  
Author(s):  
Christoph Frommen ◽  
Michael Heere ◽  
Marit D. Riktor ◽  
Magnus H. Sørby ◽  
Bjørn C. Hauback

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