A THERMODYNAMIC MODEL OF THE ADHESIVE BOND AND ITS USE FOR PREDICTING BOND PERFORMANCE

Author(s):  
W.S. Gutowski
Author(s):  
PRIYANSHU KUMAR BANERJEE ◽  
MUTHU RAM PRABHU ELENCHEZHIAN ◽  
NINA SHUTE ◽  
VAMSEE VADLAMUDI ◽  
RASSEL RAIHAN ◽  
...  

2019 ◽  
Author(s):  
Ibrahim Sarikaya ◽  
Malik Tahiyat ◽  
Ramy Harik ◽  
Tanvir Farouk ◽  
John Connell ◽  
...  

BioResources ◽  
2021 ◽  
Vol 16 (3) ◽  
pp. 5058-5082
Author(s):  
William Leggate ◽  
Maryam Shirmohammadi ◽  
Robert L. McGavin ◽  
Andrew Outhwaite ◽  
Mark Knackstedt ◽  
...  

The successful manufacturing of glulam from several important Australian commercial timbers is quite challenging due to difficulties in gluing. Improvements in adhesive bond performance of spotted gum, Darwin stringybark, and southern pine timber have been achieved using alternative pre-gluing surface machining methods, e.g., face milling and sanding-post planing, when compared to conventional planing methods. In order to improve the understanding of the effects that different surface machining methods have on adhesive bond performance, this study used micro X-ray computed tomography and microscopy to assess key adhesive bond criteria. There was a considerable loss in the amount of adhesive after the wet and dry test cycles for all species. There was also an extremely high frequency of voids in the glue lines for all species, which would negatively impact bond strength and durability. Face mill prepared timber boards resulted in thicker glue lines and greater resistance to adhesion loss, compared to boards prepared via planing. For the two hardwood species, face milling also resulted in greater adhesive penetration; however, for southern pine, there were no significant differences in adhesive penetration between the three surface machining treatments. Adhesive penetration was much deeper in southern pine compared to spotted gum and Darwin stringybark.


1987 ◽  
Vol 22 (3) ◽  
pp. 183-196 ◽  
Author(s):  
W. S. Gutowski

Forests ◽  
2021 ◽  
Vol 12 (5) ◽  
pp. 546
Author(s):  
Charles R. Frihart ◽  
Rishawn Brandon ◽  
Rebecca E. Ibach ◽  
Christopher G. Hunt ◽  
Wolfgang Gindl-Altmutter

Determining adhesive bond performance for chemically modified wood is important not only for its commercial utility but also for understanding wood bond durability. Bulking modifications occupy space inside the cell wall, limiting the space available for water. We used two bulking modifications on yellow poplar (Liriodendron tulipifera L.): acetylation (Ac), which bulks and converts a wood hydroxyl group to an ester, while butylene oxide (BO) also bulks the wood but preserves a hydroxyl group. Both result in lower water uptake; however, the loss of the hydroxyl group with Ac reduces the wood’s ability to form hydrogen and other polar bonds with the adhesives. On the other hand, the BO reaction replaces a hydroxyl group with another one along a hydrocarbon chain; thus, this product may not be harder to bond than the unmodified wood. We investigated how these chemical modifications of wood affect bond performance with four adhesives: resorcinol-formaldehyde (RF), melamine-formaldehyde (MF), emulsion polymer isocyanate (EPI), and epoxy. The ASTM D 905 bond shear strength for both dry and wet samples showed that the BO results were quite similar to the unmodified wood, but the MF and EPI performed poorly on Ac-modified wood, in contrast to the results with RF and epoxy.


2002 ◽  
Author(s):  
Rudolf Zitny ◽  
Jiří Sestak ◽  
Alexander Tsiapouris ◽  
Lothar Linke

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