Ultra-sensitive HPLC-photochemical reaction-luminol chemiluminescence method for the measurement of secondary amines after nitrosation

Abstract A novel chemiluminescence method has been developed for the determination of the organophosphorous pesticide phosphamidon in environmental water samples, based on the reaction of phosphamidon with luminolH2O2 in an alkaline medium using sodium dodecyl benzene sulfonate as the enhancer. Under optimum conditions, the increased chemiluminescence intensity was proportional to the concentration of phosphamidon in the range of 0.011.0 g/mL and the detection limit was 0.0038 g/mL (3). The relative standard deviation was <2 for 0.5 g/mL phosphamidon (n = 11). The proposed method was applied to the determination of phosphamidon residue in an environmental water sample with satisfactory results. Further study was focused on the mechanism of phosphamidon, and a possible mechanism was proposed.

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ChemInform Abstract: PHOTOCHEMICAL REACTION OF N-METHYLPHENANTHRENE-9,10-DICARBOXIMIDE WITH SECONDARY AMINES. AMINOLYSIS FROM NITROGEN-HYDROGEN ABSTRACTION

Chemischer Informationsdienst ◽

10.1002/chin.198552199 ◽

1985 ◽

Vol 16 (52) ◽

Author(s):

Y. KUBO ◽

C. EGUSA ◽

T. ARAKI

Keyword(s):

Photochemical Reaction ◽

Hydrogen Abstraction ◽

Secondary Amines

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Porphyrin-Induced Photogeneration of Hydrogen Peroxide Determined Using the Luminol Chemiluminescence Method in Aqueous Solution: A Structure-Activity Relationship Study Related to the Aggregation of Porphyrin

Analytical Sciences ◽

10.2116/analsci.22.255 ◽

2006 ◽

Vol 22 (2) ◽

pp. 255-258 ◽

Cited By ~ 19

Author(s):

Keiko KOMAGOE ◽

Takashi KATSU

Keyword(s):

Aqueous Solution ◽

Hydrogen Peroxide ◽

Structure Activity Relationship ◽

Activity Relationship ◽

Chemiluminescence Method ◽

Luminol Chemiluminescence ◽

Structure Activity ◽

Relationship Study

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A Discrepancy in Superoxide Scavenging Activity between the ESR-Spin Trapping Method and the Luminol Chemiluminescence Method

Bioscience Biotechnology and Biochemistry ◽

10.1271/bbb.70011 ◽

2007 ◽

Vol 71 (6) ◽

pp. 1505-1513 ◽

Cited By ~ 4

Author(s):

Emiko SATO ◽

Yoshimi NIWANO ◽

Takayuki MOKUDAI ◽

Masahiro KOHNO ◽

Yukihiko MATSUYAMA ◽

...

Keyword(s):

Spin Trapping ◽

Scavenging Activity ◽

Chemiluminescence Method ◽

Superoxide Scavenging Activity ◽

Luminol Chemiluminescence ◽

Esr Spin Trapping ◽

Trapping Method

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A Sensitive Chemiluminescence Procedure for the Determination of Carbon Monoxide with Myoglobin—Luminol Chemiluminescence System

Applied Spectroscopy ◽

10.1366/000370207781393398 ◽

2007 ◽

Vol 61 (7) ◽

pp. 706-710 ◽

Cited By ~ 6

Author(s):

Xiaofeng Xie ◽

Xili He ◽

Zhenghua Song

Keyword(s):

Carbon Monoxide ◽

Injection Technique ◽

Chemiluminescence Method ◽

Chemiluminescence Intensity ◽

Whole Process ◽

Enhanced Chemiluminescence ◽

Luminol Chemiluminescence ◽

Relative Standard ◽

Artificial Water

A novel chemiluminescence method combined with the flow injection technique for the determination of carbon monoxide is presented in this paper. The chemiluminescence signal based on the reaction between myoglobin and luminol in an alkaline medium was remarkably enhanced by carbon monoxide. The enhanced chemiluminescence intensity was linear with carbon monoxide concentration in the range from 0.01 to 10.0 pmol·L−1, and the detection limit was 3 × 10−3 pmol·L−1 (3σ). The whole process, including sampling and washing, could be completed in 0.5 min with a relative standard deviation of less than 4.0%. The proposed method was applied successfully in the assay of carbon monoxide in human serum and artificial water samples without any pretreatment procedure.

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