Catalytic decomposition of ammonia to COx-free hydrogen over Ni/ZSM-5 catalysts: A comparative study of the preparation methods

2018 ◽  
Vol 562 ◽  
pp. 49-57 ◽  
Author(s):  
Zhong-Pan Hu ◽  
Chen-Chen Weng ◽  
Chong Chen ◽  
Zhong-Yong Yuan
Molecules ◽  
2022 ◽  
Vol 27 (2) ◽  
pp. 503
Author(s):  
Qiangu Yan ◽  
Timothy Ketelboeter ◽  
Zhiyong Cai

Nickel (Ni)-lignin nanocomposites were synthesized from nickel nitrate and kraft lignin then catalytically graphitized to few-layer graphene-encapsulated nickel nanoparticles (Ni@G). Ni@G nanoparticles were used for catalytic decomposition of methane (CDM) to produce COx-free hydrogen and graphene nanoplatelets. Ni@G showed high catalytic activity for methane decomposition at temperatures of 800 to 900 °C and exhibited long-term stability of 600 min time-on-stream (TOS) without apparent deactivation. The catalytic stability may be attributed to the nickel dispersion in the Ni@G sample. During the CDM reaction process, graphene shells over Ni@G nanoparticles were cracked and peeled off the nickel cores at high temperature. Both the exposed nickel nanoparticles and the cracked graphene shells may participate the CDM reaction, making Ni@G samples highly active for CDM reaction. The vacancy defects and edges in the cracked graphene shells serve as the active sites for methane decomposition. The edges are continuously regenerated by methane molecules through CDM reaction.


2014 ◽  
Vol 79 (5) ◽  
pp. AB319
Author(s):  
Jong Soo Lee ◽  
Yoon Tae Jeen ◽  
Seung Han Kim ◽  
Jae MIN Lee ◽  
Hyuk Soon Choi ◽  
...  

2019 ◽  
Vol 193 ◽  
pp. 221-231 ◽  
Author(s):  
Hong Du ◽  
Xiuyun Ma ◽  
Peifang Yan ◽  
Miao Jiang ◽  
Ziang Zhao ◽  
...  

Fuel ◽  
2011 ◽  
Vol 90 (1) ◽  
pp. 430-432 ◽  
Author(s):  
R. Utrilla ◽  
J.L. Pinilla ◽  
I. Suelves ◽  
M.J. Lázaro ◽  
R. Moliner

1988 ◽  
Vol 1 (11) ◽  
pp. 361-369 ◽  
Author(s):  
J. J. Weimer ◽  
G. K. Chuah ◽  
G. Abend ◽  
N. Kruse ◽  
J. H. Block

2017 ◽  
Vol 42 (38) ◽  
pp. 24213-24221 ◽  
Author(s):  
Seetharamulu Podila ◽  
Hafedh Driss ◽  
Sharif F. Zaman ◽  
Arshid M. Ali ◽  
Abdulrahim A. Al-Zahrani ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document