One-step synthesis of dimethyl ether from the gas mixture containing CO2 with high space velocity

2012 ◽  
Vol 98 ◽  
pp. 92-101 ◽  
Author(s):  
Wei-Hsin Chen ◽  
Bo-Jhih Lin ◽  
How-Ming Lee ◽  
Men-Han Huang
2016 ◽  
Vol 25 (5) ◽  
pp. 775-781 ◽  
Author(s):  
Yan Wang ◽  
Yuexian Chen ◽  
Feng Yu ◽  
Dahai Pan ◽  
Binbin Fan ◽  
...  

2010 ◽  
Vol 19 (1) ◽  
pp. 67-72 ◽  
Author(s):  
Xiao-Ming Zheng ◽  
Jin-Hua Fei ◽  
Zhao-Yin Hou

2008 ◽  
Vol 47 (20) ◽  
pp. 7672-7679 ◽  
Author(s):  
Gholamreza Moradi ◽  
Javad Ahmadpour ◽  
Mahdi Nazari ◽  
Ferydon Yaripour

2011 ◽  
Vol 171 (1) ◽  
pp. 229-235 ◽  
Author(s):  
Guohui Yang ◽  
Montree Thongkam ◽  
Tharapong Vitidsant ◽  
Yoshiharu Yoneyama ◽  
Yisheng Tan ◽  
...  

2011 ◽  
Vol 66-68 ◽  
pp. 1404-1409 ◽  
Author(s):  
Rui Zhi Chu ◽  
Zhong Cai Zhang ◽  
Ya Fei Liu ◽  
Xian Liang Meng ◽  
Zhi Min Zong ◽  
...  

A series of Pd/γ-Al2O3 catalysts with different additons of Pd were prepared by impregnation. The effect of calcination condition and Pd loading on catalytic performance of catalysts for one-step dimethyl ether synthesis has been investigated. The physic-chemical performance and structure of Pd/γ-Al2O3 catalysts were characterized by CO-TPD, TGA and nitrogen physisorption. The results show that the dispersion of Pd and the amount of adsorbration on the CO-bridge of Pd could be increased to by the moderate microwave heating on the catalysts, and the catalyst performance can be improved. But a large number of surface acidic sites of Pd/γ-Al2O3 are covered by highly fragmented Pd-grain, it causes DME selectivity reduced. And the excessive Pd can reduce the samples’ surface acid, decrease the dispersion of the metal Pd and block up the pore of γ-Al2O3. The CO conversion rate and DME space-time yield could reach 60.1% and 28.76 mmol·g-1·h-1 respectively at 2% Pd loading, at this time Pd/γ-Al2O3 has a high Pd activity surface and ideal acid sites.


2008 ◽  
Vol 22 (5) ◽  
pp. 2877-2884 ◽  
Author(s):  
Xiu-Juan Tang ◽  
Jin-Hua Fei ◽  
Zhao-Yin Hou ◽  
Xiao-Ming Zheng ◽  
Hui Lou

2007 ◽  
Vol 115 (1-2) ◽  
pp. 23-26 ◽  
Author(s):  
Youshun Luan ◽  
Hengyong Xu ◽  
Chunying Yu ◽  
Wenzhao Li ◽  
Shoufu Hou

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