Electrochemical lithium ion storage properties of single-walled carbon nanotubes containing organic molecules

Carbon ◽  
2009 ◽  
Vol 47 (4) ◽  
pp. 1081-1086 ◽  
Author(s):  
S. Kawasaki ◽  
Y. Iwai ◽  
M. Hirose
2016 ◽  
Vol 18 (15) ◽  
pp. 10411-10418 ◽  
Author(s):  
Yosuke Ishii ◽  
Kosuke Tashiro ◽  
Kento Hosoe ◽  
Ayar Al-zubaidi ◽  
Shinji Kawasaki

We investigated the electrochemical lithium-ion storage properties of 9,10-anthraquinone (AQ) and 9,10-phenanthrenequinone (PhQ) molecules encapsulated in the inner hollow core of single-walled carbon nanotubes (SWCNTs).


RSC Advances ◽  
2017 ◽  
Vol 7 (63) ◽  
pp. 39997-40004 ◽  
Author(s):  
Jasmin Smajic ◽  
Amira Alazmi ◽  
Shashikant P. Patole ◽  
Pedro M. F. J. Costa

Structural breakdown and capacity loss of a red phosphorus-based anode material for lithium-ion batteries have been considerably attenuated with the addition of single-walled carbon nanotubes.


2020 ◽  
Vol 10 (17) ◽  
pp. 5786
Author(s):  
Dmitry A. Kolosov ◽  
Olga E. Glukhova

The incorporation of Si16 nanoclusters into the pores of pillared graphene on the base of single-walled carbon nanotubes (SWCNTs) significantly improved its properties as anode material of Li-ion batteries. Quantum-chemical calculation of the silicon-filled pillared graphene efficiency found (I) the optimal mass fraction of silicon (Si)providing maximum anode capacity; (II) the optimal Li: C and Li: Si ratios, when a smaller number of C and Si atoms captured more amount of Li ions; and (III) the conditions of the most energetically favorable delithiation process. For 2D-pillared graphene with a sheet spacing of 2–3 nm and SWCNTs distance of ~5 nm the best silicon concentration in pores was ~13–18 wt.%. In this case the value of achieved capacity exceeded the graphite anode one by 400%. Increasing of silicon mass fraction to 35–44% or more leads to a decrease in the anode capacity and to a risk of pillared graphene destruction. It is predicted that this study will provide useful information for the design of hybrid silicon-carbon anodes for efficient next-generation Li-ion batteries.


2016 ◽  
Vol 9 (3) ◽  
pp. 1095-1101 ◽  
Author(s):  
Jun Hu ◽  
Yuanchun Ji ◽  
Wei Chen ◽  
Carsten Streb ◽  
Yu-Fei Song

A universal one-step strategy for the periodic deposition of redox-active polyoxometalate nanocrystals on single-walled carbon nanotubes is reported, giving access to high-performance electrodes for lithium-ion batteries.


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