Oxidation of alkanes with hydrogen peroxide catalyzed by Schiff base complexes covalently anchored to polyoxometalate

A series of transition metal alanine-salicylaldehyde Schiff base chromium (III) complexes immobilized on MCM-41 were prepared and characterized by various physico-chemical measurements such as FIIR, XRD, HRTEM, N2 sorption and elemental analysis. The immobilized complexes were effective and stable catalysts for the epoxidation of styrene and cyclohexene with 30% hydrogen peroxide. Moreover, the metal centers were found to play important roles in the catalytic performance of immobilized complex catalysts.

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Kinetics and mechanisms of the oxidation of alcohols and hydroxylamines by hydrogen peroxide, catalyzed by methyltrioxorhenium, MTO, and the oxygen binding properties of cobalt Schiff base complexes

10.2172/770652 ◽

1999 ◽

Author(s):

Timothy Zauche

Keyword(s):

Hydrogen Peroxide ◽

Schiff Base ◽

Schiff Base Complexes ◽

Oxygen Binding ◽

Binding Properties ◽

Oxidation Of Alcohols

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Cobalt(II), copper(II), zinc(II) and palladium(II) Schiff base complexes: Synthesis, characterization and catalytic performance in selective oxidation of sulfides using hydrogen peroxide under solvent-free conditions

Polyhedron ◽

10.1016/j.poly.2015.03.041 ◽

2015 ◽

Vol 95 ◽

pp. 1-13 ◽

Cited By ~ 54

Author(s):

Mahsa Khorshidifard ◽

Hadi Amiri Rudbari ◽

Banafshe Askari ◽

Mehdi Sahihi ◽

Mostafa Riahi Farsani ◽

...

Keyword(s):

Hydrogen Peroxide ◽

Schiff Base ◽

Selective Oxidation ◽

Catalytic Performance ◽

Solvent Free ◽

Schiff Base Complexes ◽

Oxidation Of Sulfides ◽

Solvent Free Conditions

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Hydroxylation of Phenol Catalyzed by Oxovanadium(IV) of Salen-Type Schiff Base Complexes with Hydrogen Peroxide

Catalysis Letters ◽

10.1007/s10562-010-0326-z ◽

2010 ◽

Vol 136 (3-4) ◽

pp. 228-233 ◽

Cited By ~ 30

Author(s):

Tahseen A. Alsalim ◽

Jabbar S. Hadi ◽

Einas A. Al-Nasir ◽

Hanna S. Abbo ◽

Salam J. J. Titinchi

Keyword(s):

Hydrogen Peroxide ◽

Schiff Base ◽

Schiff Base Complexes ◽

Hydroxylation Of Phenol

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Synthesis and characterization of some new Schiff base complexes of group 13 elements, ab initio studies, cytotoxicity and reaction with hydrogen peroxide

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy ◽

10.1016/j.saa.2012.09.007 ◽

2013 ◽

Vol 101 ◽

pp. 394-399 ◽

Cited By ~ 7

Author(s):

Mozaffar Asadi ◽

Nooshin Savaripoor ◽

Zahra Asadi ◽

Mohammad Hadi Ghatee ◽

Fatemeh Moosavi ◽

...

Keyword(s):

Hydrogen Peroxide ◽

Schiff Base ◽

Ab Initio ◽

Schiff Base Complexes ◽

Synthesis And Characterization ◽

Group 13

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Asymmetric sulfoxidation by C1-symmetric V(IV)O(ONO) (S)-NOBIN Schiff-base vanadyl complexes

Canadian Journal of Chemistry ◽

10.1139/cjc-2019-0017 ◽

2019 ◽

Vol 97 (9) ◽

pp. 637-641 ◽

Cited By ~ 1

Author(s):

Sanmitra Barman ◽

Christopher J. Levy

Keyword(s):

Hydrogen Peroxide ◽

Schiff Base ◽

Cumene Hydroperoxide ◽

Cd Spectroscopy ◽

Schiff Base Complexes ◽

Moderate Activity ◽

Butyl Hydroperoxide ◽

Vanadyl Complexes ◽

Tert Butyl Hydroperoxide ◽

Tof Ms

C1-symmetric vanadyl Schiff-base complexes were synthesized by reacting vanadium(IV) acetylacetonate with (S)-3-[(1-(2-hydroxynaphthalen-1-yl)naphthalen-2-ylimino]methyl]-phenanthrene-4-ol and (S)-2-{[1-(2-hydroxynaphthalen-1-yl)naphthalen-2-ylimino]methyl}tetraphene-1-ol. The complexes were characterized by MALDI-TOF-MS, UV–vis, and circular dichroism (CD) spectroscopy. The catalysts showed moderate activity for the oxidation of thioanisole to methyphenylsulfoxide with hydrogen peroxide, tert-butyl hydroperoxide, and cumene hydroperoxide as the oxidants.

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