In this context,the sol-gel approach to the preparation of solid-phase microextraction fibers is applied for extracting of benzene and mathanol from enviromental water samples.Therefore,two different substances such as PEG and MWCNTs is added to the coating.PEG/MWCNTs fibers are prepared using sol-gel technology as a process.MWCNTs is immobilized as microspheres in the pores of PEG coating using Scanning Electron Microscope(SEM).At last, the results show that PEG/MWCNTs fibers are higher extraction efficiency than PEG fibers. Several factors also are considered and optimized,such as extraction temperature, extraction time,inoic strength,stirring speed,desorption temperature and desorption time.LOD(S/N=5) and LOQ(S/N=10) for sol-gel PEG/MWCNTs fibers for extraction of benzene and methanol is 1µg/L and 2µg/L, linear range is 2-2800µg/mL and 2-3000µg/L, linear correlation coefficient is 0.9937 and 0.9940, the RSDs (RSD, n = 7) is 5.1%. and 6.7%, respectively.
Bioactive organic/inorganic hybrids with improved mechanical performance