scholarly journals Bioactive organic/inorganic hybrids with improved mechanical performance

2015 ◽  
Vol 3 (7) ◽  
pp. 1379-1390 ◽  
Author(s):  
Ailing Li ◽  
Hong Shen ◽  
Huihui Ren ◽  
Chen Wang ◽  
Decheng Wu ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Mechanical Performance ◽  
Sol Gel ◽  
Poly Ethylene Glycol ◽  
Interpenetrating Networks ◽  
Poly Ethylene

New sol–gel functionalized poly-ethylene glycol (PEGM)/SiO2–CaO hybrids were prepared with interpenetrating networks of silica and PEGM through the formation of Si–O–Si bonds.

Anatase nanocrystal­dispersed thin films via sol–gel process with hot water treatment: effects of poly(ethylene glycol) addition on photocatalytic activities of the films

2001 ◽  
Vol 11 (8) ◽  
pp. 2045-2048 ◽  
Author(s):  
Yoshinori Kotani ◽  
Tatsuo Matoda ◽  
Atsunori Matsuda ◽  
Toshihiro Kogure ◽  
Masahiro Tatsumisago ◽  
...  
Keyword(s):  
Thin Films ◽  
Water Treatment ◽  
Ethylene Glycol ◽  
Sol Gel ◽  
Hot Water ◽  
Hot Water Treatment ◽  
Poly Ethylene Glycol ◽  
Sol Gel Process ◽  
Photocatalytic Activities ◽  
Poly Ethylene

Temperature-Induced Mechanomodulation of Interpenetrating Networks of Star Poly(ethylene glycol)–Heparin and Poly(N-isopropylacrylamide)

2019 ◽  
Vol 11 (45) ◽  
pp. 41862-41874 ◽  
Author(s):  
Jana Sievers ◽  
Stefan Zschoche ◽  
Ron Dockhorn ◽  
Jens Friedrichs ◽  
Carsten Werner ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Poly Ethylene Glycol ◽  
Interpenetrating Networks ◽  
Poly Ethylene

Controlled Hierarchical Pore Structures in Ethylene-Bridged Polysilsesquioxane Gels

2003 ◽  
Vol 788 ◽  
Author(s):  
Yuki Kobayashi ◽  
Kazuki Nakanishi ◽  
Kazuyuki Hirao
Keyword(s):  
Phase Separation ◽  
Ethylene Glycol ◽  
Triblock Copolymers ◽  
Sol Gel ◽  
Poly Ethylene Glycol ◽  
Bridged Polysilsesquioxane ◽  
Sol Gel Transition ◽  
Poly Ethylene ◽  
Hierarchical Pore ◽  
Gel Transition

ABSTRACTFormation of hierarchical macropores and mesopores in ethylene-bridged polysilsesquioxane sol-gel systems via concurrent sol-gel transition and phase separation induced by the incorporation of supramolecular templats has been investigated. A series of poly(ethylene-glycol)-poly(propyleneglycol)- poly(ethyleneglycol) triblock copolymers, EOPOEOs, have been employed as supramolecular templates, while 1,2-bis(trimethoxysilyl)ethane was used as a polysilsesquioxane source. Successful combination of templated mesopores and well-defined macropores due to phase-separation has been found in the system with EOPOEOs having 70 PO units and respective 20 EO units. Although similar macroporous morphology has been obtained for all the EOPOEOs with EO chain longer or shorter than 20 units, the optimum composition for the co-continuous macropores and that for templated mesopores deviated from each other, resulting in the failure of producing hierarchical macropores and mesopores.

Poly(lactic acid)/poly(ethylene glycol) stereocomplexed physical hydrogels showing thermally-induced gel–sol–gel multiple phase transitions

2018 ◽  
Vol 2 (2) ◽  
pp. 313-322 ◽  
Author(s):  
Hailiang Mao ◽  
Chen Wang ◽  
Xiaohua Chang ◽  
Heqing Cao ◽  
Guorong Shan ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Phase Transitions ◽  
Ethylene Glycol ◽  
Sol Gel ◽  
Poly Lactic Acid ◽  
Poly Ethylene Glycol ◽  
Thermally Induced ◽  
Multiple Phase ◽  
Poly Ethylene

A novel thermogel exhibiting unique thermally-induced gel–sol–gel multiple phase transitions was obtained by controlling the compositions of PLA/PEG copolymers.

Effects of poly(ethylene glycol) additive molecular weight on the microstructure and properties of sol-gel-derived lead zirconate titanate thin films

2003 ◽  
Vol 18 (3) ◽  
pp. 737-741 ◽  
Author(s):  
Shuhui Yu ◽  
Kui Yao ◽  
Santiranjan Shannigrahi ◽  
Francis Tay Eng Hock
Keyword(s):  
Thin Films ◽  
Molecular Weight ◽  
Ethylene Glycol ◽  
Lead Zirconate Titanate ◽  
Sol Gel ◽  
Lead Zirconate ◽  
Poly Ethylene Glycol ◽  
Molecular Weights ◽  
Zirconate Titanate ◽  
Poly Ethylene

Poly(ethylene glycol) (PEG) additives with different molecular weights were used to modify sol-gel precursor solutions for preparing lead zirconate titanate (PZT) thin films. The morphology, crystalline structure, and mechanical and electrical properties of the films were characterized. The relationship between the characteristics of the films and the molecular weight of PEG was investigated. It was observed that the PEG eliminated cracking of the films during multiple pyrolysis treatments. However, with the increase of the PEG molecular weight, the films became less dense, which led to decreased Young's modulus and dielectric constant and increased coercive field. Our experiments showed that films prepared from sols modified by PEG with a molecular weight of 200 exhibited a dense morphology and excellent mechanical and electric properties without cracking.

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