Anodic process of stibnite in slurry electrolysis: The direct collision oxidation

Author(s):  
Yonglu Zhang ◽  
Dingfan Qiu ◽  
Chengyan Wang ◽  
Yongqiang Chen ◽  
Zhichao Yao ◽  
...  
2003 ◽  
Vol 68 (7) ◽  
pp. 1326-1344 ◽  
Author(s):  
Francesc Estrany ◽  
Ramon Oliver ◽  
Esther García ◽  
Esther Gualba ◽  
Pere-Lluís Cabot ◽  
...  

The anodic oxidation of α-tetrathiophene on Pt was studied in a 1.0 mM monomer solution in 0.1 M LiClO4 in 45:35:20 acetonitrile/ethanol/DMF. Three consecutive oxidation peaks were detected by cyclic voltammetry, along with a cathodic peak related to the reduction of electroactive polarons formed during the first anodic process. Uniform, adherent, insoluble and black polymer films were obtained by chronoamperometry at 1.000 V vs Ag|AgCl corresponding to the first oxidation-polymerization process. Stirring of monomer solution promotes the production of polymer, favoring the oxidation of polymer chains with the incorporation of more doping ClO4- ions and ion pairs of Li+ClO4- in their monomeric units. The conductivity of the polymer obtained under stirring was three orders of magnitude higher than that synthesized from a quiescent solution. The scanning electron microscopy images also showed much more uniform films under stirring. This behavior points to the existence of less crosslinking in the polymer and the production of longer linear chains when the solution is stirred. IR analysis of these materials confirmed the formation of crosslinked chains with predominance of β-β linkages. Short linear oligomers such as the dimer, trimer and tetramer were detected in all polymers by MALDI-TOF-MS, thus showing a radical polycondensation as initial electropolymerization mechanism. A larger proportion of linear oligomers is formed under solution stirring.


Author(s):  
Motohiro Sato ◽  
Tairo Kikuchi ◽  
Kenta Murakami ◽  
Satoshi Miyashiro ◽  
Taira Okita

A linked facility between an ion accelerator and STM enabled to elucidate cascade damage process experimentally with an atomistic scale. By adjusting experimental conditions, we have successfully attained very clear images of Si (111) surface irradiated by very low-flux and stable ion beams. We can obtain the information of displacement damage produced by one injected ion. Much higher density of defects is observed than the number of injected ions throughout the area of the image, indicating that there are processes for defect formation other than direct collision with injected particles.


2020 ◽  
Vol 492 (4) ◽  
pp. 4892-4916 ◽  
Author(s):  
Travis R Yeager ◽  
Curtis Struck

ABSTRACT Splash bridges are formed from the direct inelastic collision of gas-rich galaxies. Recent multiwavelength observations of the Taffy galaxies, UGC 12914/15, have revealed complicated gas structures in the bridge. We have upgraded the sticky particle simulation code of Yeager & Struck by adding: the ability to adjust the relative inclination of the gas discs, the ability to track cloud–cloud collisions over time, and additional cooling processes. Inclination effects lead to various morphological features, including filamentary streams of gas stripped from the smaller galactic disc. The offset of disc centres at impact determines whether or not these streams flow in a single direction or multiple directions, even transverse to the motion of the two galaxies. We also find that, across many types of direct collision, independent of the inclination or offset, the distributions of weighted Mach numbers and shock velocities in colliding clouds relax to a very similar form. There is good evidence of prolonged turbulence in the gas of each splash bridge for all inclinations and offsets tested, as a result of continuing cloud collisions, which in turn are the result of shearing and differentially accelerated trajectories. The number distribution of high velocity shocks in cloud collisions, produced in our low inclination models, are in agreement with those observed by Appleton et al. in the Taffy Galaxies with ALMA.


Author(s):  
Nurhaswani Alias ◽  
Siti Azlina Rosli ◽  
Nurulhuda Bashirom ◽  
Monna Rozana ◽  
Wai Kian Tan ◽  
...  

1878 ◽  
Vol 9 ◽  
pp. 141-142 ◽  
Author(s):  
George Forbes

At various times there have arisen supporters of one or other of two extreme hypothesis concerning the nature of what we define as force. These are the hypothesis of “action at a distance” and of “no action at a distance.”According to the latter hypothesis, the centre of gravity of no body, however large or however small, can be moved from a position of rest, nor can its motion be altered in direction or amount, except by direct collision with another portion of matter.


2014 ◽  
Vol 16 (5) ◽  
pp. 2745-2753 ◽  
Author(s):  
Ai-Yong Zhang ◽  
Lu-Lu Long ◽  
Chang Liu ◽  
Wen-Wei Li ◽  
Han-Qing Yu

To prepare TiO2 single crystals by recycling the waste ethylene glycol electrolyte from the widely-used anodic process for efficient photocatalytic water treatment.


2014 ◽  
Vol 2014 (8) ◽  
pp. 664-670 ◽  
Author(s):  
V. N. Nekrasov ◽  
O. V. Limanovskaya ◽  
A. V. Suzdal’tsev ◽  
A. P. Khramov ◽  
Yu. P. Zaikov
Keyword(s):  

1974 ◽  
Vol 10 (4) ◽  
pp. 374-375
Author(s):  
V. V. Gerasimov ◽  
V. A. Shuvalov ◽  
S. A. Andreeva ◽  
Yu. V. Andreev

2010 ◽  
Vol 145 ◽  
pp. 361-364
Author(s):  
Cui Rong Liu ◽  
Tuo Sheng Jia ◽  
Qing Sen Meng

In this paper the technological experiments of static bonding has been carried out in the bonding of multi-layer Pyrex7740 Glass and Al. The joining mechanism is analyzed with SEM and EDX. It’s observed that bonding region across the interface consists of the metal layer, oxide transitional layer and the glass layer. The bonding process can mainly be categorized into anodic process and solid state diffusing process. The pile-up of the ions and its drift in the interface area are the main reasons for anode oxidation and joining successfully. The analysis of the shear stress and deformation in the static bonded samples was made by MARC. Modeling studies showed the maximum shear stress of bonded samples all occur in the transition layer. It also shows the shear stress and deformation in the three-layer samples is significantly smaller than that in the two-layer samples. This has an important advantage in MEMS fabrication.


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