Hydrogen Isotopes Permeation in Clean or Unoxidized FeCrAl Alloys: A Review

The US Department of Energy is working with fuel vendors to develop accident tolerant fuels (ATF) for the current fleet of light water reactors (LWRs). The ATF should be more resilient to loss of coolant accident scenarios and help extending the life of the operating LWRs. One of the proposed ATF concepts is to use iron-chromium-aluminum (FeCrAl) alloys for the cladding of the fuel. A concern in using ferritic FeCrAl is that this type of cladding may result in an increase in the concentration of tritium in the coolant. The objective of the current critical review is to collect and assess information from the literature regarding diffusion or permeation of hydrogen (H) and its isotopes deuterium (D) and Tritium (T) across industrial alloys (including FeCrAl) used or intended for the nuclear industry. Over a hundred years of data reviewed shows that the solubility of hydrogen in ferritic alloys is lower than in austenitic alloys but hydrogen permeates faster through a ferritic material than through austenitic materials. The tritium permeation rates in FeCrAl alloys are between those in austenitic stainless steels and in ferritic FeCr steels. The activation energy for hydrogen permeation is approximately 30 pct higher in the austenitic alloys compared with the ferritic (typically ∼ 50 kJ/mol in ferritic vs. ∼ 65 kJ/mol in the austenitic). None of the major elements in FeCrAl alloys react with hydrogen to form detrimental hydride phases. The effect of surface oxides on FeCrAl delaying hydrogen entrance into FeCrAl alloy is not part of this review.

Effects of temperature and load during hot impression behavior of Cr-Ni stainless steel

Austenitic Stainless steels are majorly used because of their high resistance to aqueous corrosion and high temperature properties. Some major applications of stainless steels at high temperatures include engine and exhaust components in aircrafts, recuperators in steel mills, and pulverized coal injection lances for blast furnaces. In all the above said applications, the components are constantly subjected to loads and high temperatures. This makes the study of their creep behavior very important to decide the life of the component. Cr-Ni stainless steel was used as a starting material, and hot impression creep test was performed on cylindrical samples of 10 mm height and 15 mm diameter for a dwell time of 150 min at two different loads of 84 and 98 MPa and at two different temperatures 450 and 500 °C. The time vs. indentation depth was plotted, and creep rate was calculated in each case. It was observed that with an increase in time, creep rate increased in the primary creep region and remained almost constant in the secondary creep region irrespective of temperature and load. The indentation depth and creep rate increased with an increase in load and temperature.

Complex Material and Surface Analysis of Anterolateral Distal Tibial Plate of 1.4441 Steel

Nickel-based austenitic stainless steels are still common for manufacture of implants intended for acute hard tissue reinforcement or stabilization, but the risk of negative reactions due to soluble nickel-rich corrosion products must be considered seriously. Corrosion processes may even be accelerated by the evolution of microstructure caused by excessive heat during machining, etc. Therefore, this study also deals with the investigation of microstructure and microhardness changes near the threaded holes of the anterolateral distal tibial plate containing approx. 14wt.% Ni by composition. There were only insignificant changes of microhardness, grain size, or microstructure orientation found close to the area of machining. In addition, wettability measurements of surface energy demonstrated only minor differences for bulk material and areas close to machining. The cyclic potentiodynamic polarization tests were performed in isotonic physiological solution. The first cycle was used for the determination of corrosion characteristics of the implant after chemical passivation, the second cycle was used to simulate real material behavior under the condition of previous surface damage by excessive pitting corrosion occurring during previous polarization. It was found that the damaged and spontaneously repassived surface showed a three-time higher standard corrosion rate than the “as received” chemically passivated surface. One may conclude that previous surface damage may decrease the lifetime of the implant significantly and increase the amount of nickel-based corrosion products distributed into surrounding tissues.

High Temperature Fatigue of Aged Heavy Section Austenitic Stainless Steels

This work investigates two austenitic stainless steels, Sanicro 25 which is a candidate for high temperature heavy section components of future power plants and Esshete 1250 which is used as a reference material. The alloys were subjected to out-of-phase (OP) thermomechanical fatigue (TMF) testing under strain-control in the temperature range of 100 ∘C to 650 ∘C. Both unaged and aged (650 ∘C, 3000 h) TMF specimens were tested to simulate service degradation resulting from long-term usage. The scanning electron microscopy methods electron backscatter diffraction (EBSD) and energy dispersive spectroscopy (EDS) were used to analyse and discuss active failure and deformation mechanisms. The Sanicro 25 results show that the aged specimens suffered increased plastic straining and shorter TMF-life compared to the unaged specimens. The difference in TMF-life of the two test conditions was attributed to an accelerated microstructural evolution that provided decreased the effectiveness for impeding dislocation motion. Ageing did not affect the OP-TMF life of the reference material, Esshete 1250. However, the structural stability and its resistance for cyclic deformation was greatly reduced due to coarsening and cracking of the strengthening niobium carbide precipitates. Sanicro 25 showed the higher structural stability during OP-TMF testing compare with the reference material.

Effect of plasma nitriding of austenitic stainless steel produced by direct metal laser sintering

A special additive manufacturing (AM), called as Direct Metal Laser Sintering (DMLS), is a technology that produces 3D workpieces using a wide range of different metals as raw materials. The aim of current research is to investigate the plasma nitriding effect on the DMLS produced samples. The direct current plasma nitriding treatment was achieved at 440 °C for 4 hours with 75%N2 – 25%H2 gas mixture. Before the treatment, the 316L austenitic stainless steels samples were ground with different methods to modify the surface roughness. Scanning electron microscope (SEM), X-ray diffractometer, glow discharge optical electron spectroscopy, Vickers microhardness tester and potentiodynamic corrosion test were used for the characterization of surface properties. The results demonstrated that the surface roughness did not affect the outcome of the plasma nitriding, but the corrosion resistance increases with the decrease of the surface roughness compared to the untreated 3D sample.

A review of progress on high nitrogen austenitic stainless-steel research

High nitrogen austenitic stainless steels are commonly used in wide range of applications because of their excellent properties, attracting super attention over the past decades. Compared with other metal materials, high nitrogen austenitic stainless steel increases the nitrogen content under the premise that the structure is austenite, giving it excellent mechanical properties and corrosion resistance. Based on relevant documents from the past ten years, this article summarizes and compares three preparation methods for high nitrogen austenitic stainless steels, namely: powder nitriding, melt nitriding and bulk nitriding. They can be divided into six categories according to other differences as explained by the latest research progress on strengthening and toughening mechanism for high nitrogen austenitic stainless steels: composite structure strengthening, fine grain strengthening, precipitation strengthening and strain strengthening. This article also reviews the research progress on excellent properties of high nitrogen stainless steel, including strength, hardness and corrosion resistance. It further describes the emerging nickel-free high nitrogen austenitic stainless steels and its biocompatibility. Welding applications of high nitrogen austenitic stainless steels are also described from three aspects: friction stir welding, arc welding and brass solder. Finally, this article puts forward the development direction of high nitrogen austenitic stainless steels in the future.

Surface Modification of a Nickel-Free Austenitic Stainless Steel by Low-Temperature Nitriding

Low-temperature nitriding allows to improve surface hardening of austenitic stainless steels, maintaining or even increasing their corrosion resistance. The treatment conditions to be used in order to avoid the precipitation of large amounts of nitrides are strictly related to alloy composition. When nickel is substituted by manganese as an austenite forming element, the production of nitride-free modified surface layers becomes a challenge, since manganese is a nitride forming element while nickel is not. In this study, the effects of nitriding conditions on the characteristics of the modified surface layers obtained on an austenitic stainless steel having a high manganese content and a negligible nickel one, a so-called nickel-free austenitic stainless steel, were investigated. Microstructure, phase composition, surface microhardness, and corrosion behavior in 5% NaCl were evaluated. The obtained results suggest that the precipitation of a large volume fraction of nitrides can be avoided using treatment temperatures lower than those usually employed for nickel-containing austenitic stainless steels. Nitriding at 360 and 380 °C for duration up to 5 h allows to produce modified surface layers, consisting mainly of the so-called expanded austenite or gN, which increase surface hardness in comparison with the untreated steel. Using selected conditions, corrosion resistance can also be significantly improved.