Guided by the insertion of coordination sites within ligands, an interpenetrated metal–organic framework (MOFs) NKU-112 and a self-penetrated framework NKU-113 were obtained. The enhanced stability and porosity of NKU-113 prove the efficiency of the method for the structure and properties modulation of penetrated MOFs.
In this contribution, by inserting a ligand intoCo-MOF1, the reformed aggregation of triangle grids (Co-MOF1-tpt) shows enhanced stability. In addition, owing to the maintenance of porosity,Co-MOF1-tptalso reveals a certain CO2storage ability and CO2/CH4adsorption selectivity as expected.
A tripodal linker with six pendant methylthio (-SCH3) groups was crystallized with Zn(II) ions to provide metal-organic framework (MOF) crystals, namely NOTT-6SMe-Zn, bearing three kinds of cage-like pores. NOTT-6SMe-Zn gives...
A new 3D zeolite-like MOF [Na8(N5)8(H2O)3]n with an enhanced stability has been successfully synthesized by the self-assembly of Na+ with cyclo-N5− ligands.
We review the general principle of the design and functional modulation of nanoscaled MOF heterostructures, and biomedical applications in enhanced therapy.
Enhancing the stability and porosity of penetrated metal–organic frameworks through the insertion of coordination sites