Ideal thermodynamic behaviors of aqueous electrolyte solutions at very high concentrations

2020 ◽  
Vol 759 ◽  
pp. 137941 ◽  
Author(s):  
Andreas A. Zavitsas
Author(s):  
Jaecheol Choi ◽  
Hoang-Long Du ◽  
Manjunath Chatti ◽  
Bryan H. R. Suryanto ◽  
Alexandr Simonov ◽  
...  

We demonstrate that bismuth exhibits no measurable electrocatalytic activity for the nitrogen reduction reaction to ammonia in aqueous electrolyte solutions, contrary to several recent reports on the highly impressive rates of Bi-catalysed electrosynthesis of NH<sub>3</sub> from N<sub>2</sub>.


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