Correlation of Thermodynamic Data for Aqueous Electrolyte Solutions to Very High Ionic Strength Using INSIGHT: Vapor Saturated Water Activity in the System CaCl2-H2O to 250°C and Solid Saturation

1998 ◽  
Vol 19 (3) ◽  
pp. 761-770 ◽  
Author(s):  
S. M. Sterner ◽  
A. R. Felmy ◽  
C. S. Oakes ◽  
K. S. Pitzer
Keyword(s):  
Ionic Strength ◽  
Water Activity ◽  
Thermodynamic Data ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
High Ionic Strength ◽  
Aqueous Electrolyte Solutions ◽  
Saturated Water ◽  
Very High

Promoting Nitrogen Electroreduction to Ammonia with Bismuth Nanocrystals and Potassium Cations in Water

2020 ◽  
Author(s):  
Jaecheol Choi ◽  
Hoang-Long Du ◽  
Manjunath Chatti ◽  
Bryan H. R. Suryanto ◽  
Alexandr Simonov ◽  
...  
Keyword(s):  
Electrocatalytic Activity ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Reduction Reaction ◽  
Nitrogen Reduction ◽  
Aqueous Electrolyte Solutions

We demonstrate that bismuth exhibits no measurable electrocatalytic activity for the nitrogen reduction reaction to ammonia in aqueous electrolyte solutions, contrary to several recent reports on the highly impressive rates of Bi-catalysed electrosynthesis of NH<sub>3</sub> from N<sub>2</sub>.

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