Preparation and characterization of molybdenum hexacarbonyl encapsulated in polystyrene and its application as an efficient and reusable catalyst for epoxidation of alkenes with tert-BuOOH

2011 ◽  
Vol 14 (6) ◽  
pp. 604-610 ◽  
Author(s):  
Shahram Tangestaninejad ◽  
Majid Moghadam ◽  
Valiollah Mirkhani ◽  
Iraj Mohammadpoor-Baltork ◽  
Maryam Torki
2021 ◽  
Author(s):  
Mojgan Zendehdel ◽  
Fatemeh Tavakoli

Abstract A new class of catalyst has been prepared with sulfunic acid functionalized HY zeolite (HY-N-SO3H) and characterized by FESEM, TEM, FTIR, TGA, XRD and BET. The result show that the catalyst has the micro-meso structure without ordering in the mesophase. Then, two sets of organic reaction were examined to consider of catalytic activity. The micro-meso structure HY-N-SO3H was used as an acidic catalyst to synthesis of coumarins via Pechmann reaction and facile transformation of amines to formamides under solvent free condition. This catalyst was compared with NaY-N-SO3H and MCM-N-SO3H and pure porous material to consider of the effect of acidity and kind and size of porous in the catalyst. The significant advantages of HY-N-SO3H respect to other catalyst are short reaction times, high yields, pure products, mild conditions and easy workup. In addition, we report an original and environmentally friendly solvent-free procedures which reusability of catalyst makes this method nearly green and environmental friendly.


2020 ◽  
Vol 44 (13) ◽  
pp. 5056-5063
Author(s):  
Amir Hossein Ghasemi ◽  
Hossein Naeimi

The aerogel nanocomposite produces using the sol–gel and supercritical drying method processes. The CO2 supercritical drying (SCD) was taken as the most powerful process, ensuring the best properties of the product.


2015 ◽  
Vol 54 (15) ◽  
pp. 7139-7141 ◽  
Author(s):  
Connor A. Koellner ◽  
Nicholas A. Piro ◽  
W. Scott Kassel ◽  
Christian R. Goldsmith ◽  
Christopher R. Graves

2016 ◽  
Vol 40 (7) ◽  
pp. 6171-6184 ◽  
Author(s):  
Beheshteh Asadi ◽  
Iraj Mohammadpoor-Baltork ◽  
Shahram Tangestaninejad ◽  
Majid Moghadam ◽  
Valiollah Mirkhani ◽  
...  

A novel method for synthesis of aminonaphthoquinone derivatives using Fe3O4@TDSN–Bi(iii) is reported.


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