A novel polyvinylidene fluoride/microfiber composite gel polymer electrolyte with an interpenetrating network structure for lithium ion battery

2014 ◽  
Vol 125 ◽  
pp. 450-456 ◽  
Author(s):  
Jinglei Hao ◽  
Qizhen Xiao ◽  
Gangtie Lei ◽  
Zhaohui Li ◽  
Lijun Wu
Keyword(s):  
Lithium Ion Battery ◽  
Polymer Electrolyte ◽  
Network Structure ◽  
Polyvinylidene Fluoride ◽  
Gel Polymer Electrolyte ◽  
Lithium Ion ◽  
Interpenetrating Network ◽  
Composite Gel

scholarly journals A Novel Gel Polymer Electrolyte by Thiol-Ene Click Reaction Derived from CO2-Based Polycarbonate for Lithium-Ion Batteries

2020 ◽  
Vol 2020 ◽  
pp. 1-12
Author(s):  
Wenhan Luo ◽  
Kuirong Deng ◽  
Shuanjin Wang ◽  
Shan Ren ◽  
Dongmei Han ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Polymer Electrolyte ◽  
Polyvinylidene Fluoride ◽  
Lithium Iron Phosphate ◽  
Click Reaction ◽  
Gel Polymer Electrolyte ◽  
Lithium Ion ◽  
Liquid Lithium ◽  
Methoxypolyethylene Glycol ◽  
Composite Gel

Here, we describe the synthesis of a CO2-based polycarbonate with pendent alkene groups and its functionalization by grafting methoxypolyethylene glycol in view of its application possibility in gel polymer electrolyte lithium-ion batteries. The gel polymer electrolyte is prepared by an in-situ thiol-ene click reaction between polycarbonate with pendent alkene groups and thiolated methoxypolyethylene glycol in liquid lithium hexafluorophosphate electrolyte and exhibits conductivity as remarkably high as 2.0×10−2 S cm−1 at ambient temperature. To the best of our knowledge, this gel polymer electrolyte possesses the highest conductivity in all relevant literatures. A free-standing composite gel polymer electrolyte membrane is obtained by incorporating the gel polymer electrolyte with electrospun polyvinylidene fluoride as a skeleton. The as-prepared composite membrane is used to assemble a prototype lithium iron phosphate cell and evaluated accordingly. The battery delivers a good reversible charge-discharge capacity close to 140 mAh g-1 at 1 C rate and 25°C with only 0.022% per cycle decay after 200 cycles. This work provides an interesting molecular design for polycarbonate application in gel electrolyte lithium-ion batteries.

A composite gel polymer electrolyte with high voltage cyclability for Ni-rich cathode of lithium-ion battery

2015 ◽  
Vol 61 ◽  
pp. 32-35 ◽  
Author(s):  
Pu Hu ◽  
Jianghui Zhao ◽  
Tianshi Wang ◽  
Chaoqun Shang ◽  
Junnan Zhang ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Polymer Electrolyte ◽  
High Voltage ◽  
Gel Polymer Electrolyte ◽  
Lithium Ion ◽  
Composite Gel

A flexible Cellulose/Methylcellulose gel polymer electrolyte endowing superior Li+ conducting property for lithium ion battery

2020 ◽  
Vol 246 ◽  
pp. 116622 ◽  
Author(s):  
Feng Yu ◽  
Hongbing Zhang ◽  
Lingzhu Zhao ◽  
Zhipeng Sun ◽  
Yuli Li ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Polymer Electrolyte ◽  
Gel Polymer Electrolyte ◽  
Lithium Ion ◽  
Conducting Property
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