X-ray absorption near edge structure analysis of the charge–discharge mechanisms of dithiobiuret polymer used as a high-capacity cathode material for lithium-ion batteries

2018 ◽  
Vol 281 ◽  
pp. 99-108 ◽  
Author(s):  
Hiroshi Uemachi ◽  
Yuske Tamenori ◽  
Tetsuya Itono ◽  
Takashi Masuda ◽  
Tatsuya Shimoda ◽  
...  
2008 ◽  
Vol 34 (4) ◽  
pp. 859-862 ◽  
Author(s):  
Takamasa Nonaka ◽  
Chikaaki Okuda ◽  
Yoshiki Seno ◽  
Kunihito Koumoto ◽  
Yoshio Ukyo

2016 ◽  
Vol 124 (6) ◽  
pp. 659-663 ◽  
Author(s):  
Takashi TERANISHI ◽  
Yumi YOSHIKAWA ◽  
Ryota MIYAHARA ◽  
Hidetaka HAYASHI ◽  
Akira KISHIMOTO ◽  
...  

2009 ◽  
Vol 180 (20-22) ◽  
pp. 1215-1219 ◽  
Author(s):  
Yi-Chun Chen ◽  
Jin-Ming Chen ◽  
Chia-Haw Hsu ◽  
Jyh-Fu Lee ◽  
Jien-Wei Yeh ◽  
...  

2011 ◽  
Vol 347-353 ◽  
pp. 3658-3661
Author(s):  
Zhe Li ◽  
Kai Zhu ◽  
Yu Hui Wang ◽  
Gang Li ◽  
Gang Chen ◽  
...  

The Li[Li0.2Co0.4Mn0.4]O2 cathode material was prepared by a sol-gel method. The X-ray diffraction (XRD) spectroscopic showed that the material was a solid solution of LiCoO2 and Li2MnO3. The material showed a reversible discharge capacity of 155.6 mAhg−1 in the voltage window of 2.0-4.3 V after percharge to 4.6 V. While the material cycled in the same voltage window without precharge could only deliver capacity of 77.6 mAhg−1. This high capacity was attributed to the loss of oxygen and structural rearrangement in the precharge process.


2011 ◽  
Vol 04 (03) ◽  
pp. 299-303 ◽  
Author(s):  
ZHUO TAN ◽  
PING GAO ◽  
FUQUAN CHENG ◽  
HONGJUN LUO ◽  
JITAO CHEN ◽  
...  

A multicomponent olivine cathode material, LiMn0.4Fe0.6PO4 , was synthesized via a novel coprecipitation method of the mixed transition metal oxalate. X-ray diffraction patterns indicate that carbon-coated LiMn0.4Fe0.6PO4 has been prepared successfully and that LiMn0.4Fe0.6PO4/C is crystallized in an orthorhombic structure without noticeable impurity. Homogeneous distribution of Mn and Fe in LiMn0.4Fe0.6PO4/C can be observed from the scanning electron microscopy (SEM) and the corresponding energy dispersive X-ray spectrometry (EDS) analysis. Hence, the electrochemical activity of each transition metal in the olivine synthesized via coprecipitation method was enhanced remarkably, as indicated by the galvanostatic charge/discharge measurement. The synthesized LiMn0.4Fe0.6PO4/C exhibits a high capacity of 158.6 ± 3 mAhg-1 at 0.1 C, delivering an excellent rate capability of 122.6 ± 3 mAhg-1 at 10 C and 114.9 ± 3 mAhg-1 at 20 C.


2021 ◽  
pp. 103512
Author(s):  
Zaowen Zhao ◽  
Bao Zhang ◽  
Jingtian Zou ◽  
Pengfei Li ◽  
Zihang Liu ◽  
...  

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