K Doping as a Rational Method to Enhance the Sluggish Air-electrode Reaction Kinetics for Proton-Conducting Solid Oxide Cells

2021 ◽  
pp. 138453
Author(s):  
Yi Yang ◽  
Nai Shi ◽  
Yun Xie ◽  
Xinyu Li ◽  
Xueyu Hu ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
Electrode Reaction ◽  
Rational Method ◽  
Solid Oxide ◽  
Air Electrode ◽  
Proton Conducting

ChemInform Abstract: Reaction Kinetics and Microstructure of the Solid Oxide Fuel Cells Air Electrode La0.6Ca0.4MnO3/YSZ.

ChemInform ◽  
2010 ◽  
Vol 22 (40) ◽  
pp. no-no ◽  
Author(s):  
J. MIZUSAKI ◽  
H. TAGAWA ◽  
K. TSUNEYOSHI ◽  
A. SAWATA
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Reaction Kinetics ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Air Electrode

New, Efficient, and Reliable Air Electrode Material for Proton-Conducting Reversible Solid Oxide Cells

2018 ◽  
Vol 10 (2) ◽  
pp. 1761-1770 ◽  
Author(s):  
Daoming Huan ◽  
Nai Shi ◽  
Lu Zhang ◽  
Wenzhou Tan ◽  
Yun Xie ◽  
...  
Keyword(s):  
Electrode Material ◽  
Solid Oxide ◽  
Air Electrode ◽  
Proton Conducting

Reaction Kinetics and Microstructure of the Solid Oxide Fuel Cells Air Electrode La0.6Ca0.4MnO3 /  YSZ

1991 ◽  
Vol 138 (7) ◽  
pp. 1867-1873 ◽  
Author(s):  
Junichiro Mizusaki ◽  
Hiroaki Tagawa ◽  
Kikuji Tsuneyoshi ◽  
Akihiro Sawata
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Reaction Kinetics ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Air Electrode

Pr0.5Ba0.5Co0.7Fe0.25Nb0.05O3-δ as air electrode for solid oxide steam electrolysis cells

2019 ◽  
Vol 44 (42) ◽  
pp. 23539-23546 ◽  
Author(s):  
Ze-Tian Tao ◽  
Yan-Mei Jiang ◽  
Libin Lei ◽  
Fanglin Chen
Keyword(s):  
Solid Oxide ◽  
Air Electrode ◽  
Electrolysis Cells

High Cu content LaNi1-xCuxO3-δ perovskites as candidate air electrode materials for Reversible Solid Oxide Cells

2020 ◽  
Vol 45 (53) ◽  
pp. 29449-29464
Author(s):  
Anna Niemczyk ◽  
Kun Zheng ◽  
Kacper Cichy ◽  
Katarzyna Berent ◽  
Kathrin Küster ◽  
...  
Keyword(s):  
Electrode Materials ◽  
Solid Oxide ◽  
Air Electrode ◽  
Cu Content

Multielectron Electrode Reaction Kinetics with RDE and RRDE: An Advanced Electrochemical Laboratory Experiment

2021 ◽  
Author(s):  
Chengjun Li ◽  
Qizheng Zheng ◽  
Qin Xiang ◽  
Li Yu ◽  
Peng Chen ◽  
...  
Keyword(s):  
Laboratory Experiment ◽  
Reaction Kinetics ◽  
Electrode Reaction

scholarly journals Direct-Hydrocarbon Proton-Conducting Solid Oxide Fuel Cells

2021 ◽  
Vol 13 (9) ◽  
pp. 4736
Author(s):  
Fan Liu ◽  
Chuancheng Duan
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Solid Oxide ◽  
Sulfur Poisoning ◽  
Oxide Fuel ◽  
Power Sources ◽  
Proton Conducting ◽  
Conducting Oxides ◽  
Operating Temperatures ◽  
Ion Conducting

Solid oxide fuel cells (SOFCs) are promising and rugged solid-state power sources that can directly and electrochemically convert the chemical energy into electric power. Direct-hydrocarbon SOFCs eliminate the external reformers; thus, the system is significantly simplified and the capital cost is reduced. SOFCs comprise the cathode, electrolyte, and anode, of which the anode is of paramount importance as its catalytic activity and chemical stability are key to direct-hydrocarbon SOFCs. The conventional SOFC anode is composed of a Ni-based metallic phase that conducts electrons, and an oxygen-ion conducting oxide, such as yttria-stabilized zirconia (YSZ), which exhibits an ionic conductivity of 10−3–10−2 S cm−1 at 700 °C. Although YSZ-based SOFCs are being commercialized, YSZ-Ni anodes are still suffering from carbon deposition (coking) and sulfur poisoning, ensuing performance degradation. Furthermore, the high operating temperatures (>700 °C) also pose challenges to the system compatibility, leading to poor long-term durability. To reduce operating temperatures of SOFCs, intermediate-temperature proton-conducting SOFCs (P-SOFCs) are being developed as alternatives, which give rise to superior power densities, coking and sulfur tolerance, and durability. Due to these advances, there are growing efforts to implement proton-conducting oxides to improve durability of direct-hydrocarbon SOFCs. However, so far, there is no review article that focuses on direct-hydrocarbon P-SOFCs. This concise review aims to first introduce the fundamentals of direct-hydrocarbon P-SOFCs and unique surface properties of proton-conducting oxides, then summarize the most up-to-date achievements as well as current challenges of P-SOFCs. Finally, strategies to overcome those challenges are suggested to advance the development of direct-hydrocarbon SOFCs.

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