Efficient resolution of a chiral alcohol (RS)-HMPC by enzymatic transesterification with vinyl acetate using surfactant-modified lipase

2004 ◽  
Vol 34 (5) ◽  
pp. 523-528 ◽  
Author(s):  
Hui-Yuan Wu ◽  
Jian-He Xu ◽  
Suk-Fong Tsang
2012 ◽  
Vol 33 (4) ◽  
pp. 539-546
Author(s):  
Katarzyna Dąbkowska ◽  
Maciej Pilarek ◽  
Krzysztof W. Szewczyk

Kinetic resolution of (R)- and (S)-mandelic acid by its transesterification with vinyl acetate catalysed by Burholderia cepacia lipase has been studied. The influence of the initial substrate concentration on the kinetics of process has been investigated. A modified ping-pong bi-bi model of enzymatic transesterification of (S)-mandelic acid including substrate inhibition has been developed. The values of kinetic parameters of the model have been estimated. We have shown that the inhibition effect revealed over a certain threshold limit value of the initial concentration of substrate.


Author(s):  
M.A. Nisbet ◽  
S. Schmeller

AbstractBoth the vapour and particulate phases of tobacco smoke have been shown to retard benzoyI-peroxide-initiated polymerisation of vinyl acetate by interception of the radicals involved in the polymerisation process. The extent of inhibition of polymerisation by test compounds is estimated by measuring time taken for a mixture of monomer and benzoyl peroxide, immersed in a water-bath at 70°C, to reach a spontaneous boil and comparing it with the time required for a similar mixture with added retarder to reach boiling point. Units are expressed as minutes of inhibition per part per million of inhibitor × 10


2019 ◽  
Vol 12 (04) ◽  
pp. 1803-1809
Author(s):  
A. Kaviarasi ◽  
M.V.L. Kumari ◽  
A.R. Prabakaran ◽  
A. Anandavadivel

2018 ◽  
Vol 10 (5) ◽  
pp. 05043-1-05043-3 ◽  
Author(s):  
Rahul Kumar ◽  
◽  
Shashwata Chattopadhyay ◽  
Chetan Singh Solanki ◽  
Sarita Zele ◽  
...  

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