Mass-dependent fractionation of titanium stable isotopes during intensive weathering of basalts

2022 ◽  
Vol 579 ◽  
pp. 117347
Author(s):  
Xinyue He ◽  
Jinlong Ma ◽  
Gangjian Wei ◽  
Zhibing Wang ◽  
Le Zhang ◽  
...  
2019 ◽  
Vol 484 (4) ◽  
pp. 460-463
Author(s):  
N. A. Goryachev ◽  
A. V. Ignatiev ◽  
T. A. Velivetskaya ◽  
A. E. Budyak ◽  
Yu. I. Tarasova

The experience of LA—ICP determining of the isotopic composition of sulfur pyrite and arsenopyrite of gold deposits of the Baikal-patomsky plateau is considered. The technique is characterized. It is shown that all the studied samples have values δ34S and δ33S strictly corresponding to the law of mass-dependent fractionation of sulfur isotopes. A regular alleviation of the isotopic composition of sulfur of pyrite as its crystals grow for Sukhoi Log and the isotopic homogeneity of pyrite and pyrrhotite of the Golets Vysokhashiy deposit are established. It is concluded that the possible role of metamorphism of the Mamsko-Oronsky belt in the formation of isotopic homogeneity of ore sulfides.


2019 ◽  
Vol 16 (16) ◽  
pp. 3197-3205
Author(s):  
Jocelyn E. Egan ◽  
David R. Bowling ◽  
David A. Risk

Abstract. Earth system scientists working with radiocarbon in organic samples use a stable carbon isotope (δ13C) correction to account for mass-dependent fractionation, but it has not been evaluated for the soil gas environment, wherein both diffusive gas transport and diffusive mixing are important. Using theory and an analytical soil gas transport model, we demonstrate that the conventional correction is inappropriate for interpreting the radioisotopic composition of CO2 from biological production because it does not account for important gas transport mechanisms. Based on theory used to interpret δ13C of soil production from soil CO2, we propose a new solution for radiocarbon applications in the soil gas environment that fully accounts for both mass-dependent diffusion and mass-independent diffusive mixing.


2015 ◽  
Vol 49 (3) ◽  
pp. 1365-1373 ◽  
Author(s):  
Vincent Perrot ◽  
Romain Bridou ◽  
Zoyne Pedrero ◽  
Remy Guyoneaud ◽  
Mathilde Monperrus ◽  
...  

2014 ◽  
Vol 29 (12) ◽  
pp. 2284-2293 ◽  
Author(s):  
Thomas Breton ◽  
Ghylaine Quitté

A new method for high precision measurements of W stable isotopes by MC-ICPMS enables to discriminate small mass-dependent fractionations, with applications in numerous fields of earth, planetary and environmental sciences.


Primitive meteorites contain a variety of trapped noble gas components, differing in isotopic composition, host phase, and release temperature. The major components can be plausibly derived from solar noble gases by mass-dependent fractionation, but some minor components require nuclear processes and may be of presolar origin. Two such presolar components are two varieties of ‘Ne-E ’ (nearly pure 22 Ne, probably from the decay of 2.6 a 22 Na), residing in micron-sized grains of spinel and a carbonaceous phase, apparently a carbyne. A third is s -process Xe and Kr, enriched in isotopes 128, 130, 132 and 82, 84, 86. All seem to be condensates from highly evolved stars, that found their way into the early Solar System and survived in primitive meteorites. A more controversial component is ‘CCFXe’, enriched up to twofold in the heavy Xe isotopes, and attributed either to fission of an extinct, superheavy element ( Z = 111 - 115) or to direct nucleosynthesis in a supernova. Its host phases, chromite and carbynes, show none of the other isotopic anomalies expected for a supernova origin, and several other lines of evidence likewise favour a local over an exotic origin. However, conclusive proof is still lacking. To establish the true nature of these components, their host phases must be isolated, a task that is made difficult by their low abundance (0.1-1 % (by mass)), small grain size (0.01-1 μm) and uncertain composition. The most fruitful approach has been a combination of chemical techniques (etching, selective dissolution) and conventional physical methods of mineral separation.


2020 ◽  
Vol 640 ◽  
pp. A74
Author(s):  
S. Spezzano ◽  
C. Codella ◽  
L. Podio ◽  
C. Ceccarelli ◽  
P. Caselli ◽  
...  

Context. Contrary to what is expected from models of Galactic chemical evolution, the isotopic fractionation of silicon (Si) in the Galaxy has recently been found to be constant. This finding calls for new observations, also at core scales, to re-evaluate the fractionation of Si. Aims. L1157-B1 is one of the outflow-shocked regions along the blue-shifted outflow that is driven by the Class 0 protostar L1157-mm. It is an ideal laboratory for studying the material ejected from the grains on very short timescales because its chemical composition is representative of the composition of the grains. Methods. We imaged 28SiO, 29SiO, and 30SiO J = 2–1 emission towards L1157-B1 and B0 with the NOrthern Extended Millimeter Array (NOEMA) interferometer as part of the Seeds of Life in Space (SOLIS) large project. We present here a study of the isotopic fractionation of SiO towards L1157-B1. Furthermore, we used the high spectral resolution observations on the main isotopologue, 28SiO, to study the jet impact on the dense gas. We here also present single-dish observations obtained with the IRAM 30 m telescope and Herschel-HIFI. We carried out a non-local thermal equilibrium analysis using a large velocity gradient code to model the single-dish observations. Results. From our observations we can show that (i) the 2–1 transition of the main isotopologue is optically thick in L1157-B1 even at high velocities, and (ii) the [29SiO/30SiO] ratio is constant across the source, and consistent with the solar value of 1.5. Conclusions. We report the first isotopic fractionation maps of SiO in a shocked region and show the absence of a mass-dependent fractionation in 29Si and 30Si across L1157-B1. A high-velocity bullet in 28SiO has been identified, showing the signature of a jet impacting on the dense gas. With the dataset presented in this paper, both interferometric and single-dish, we were able to study the gas that is shocked at the B1a position and its surrounding gas in great detail.


1987 ◽  
Vol 120 ◽  
pp. 485-491
Author(s):  
N. Bhandari

A large number of elements in certain meteorites have isotopic composition different from that existing in rocks of the earth or the moon. Excess amounts of some isotopes, which are radiogenic daughters, are attributed to the in situ decay of their parent nuclide. Material containing radioactive parents is believed to have been injected into the condensing solar nebula, from astrophysical sites of their production shortly before formation of these grains. Other isotopic anomalies do not show mass dependent pattern which is characteristic of chemical fractionation. They must be primary isotopic abundances, if it is assumed that physico-chemical processes in the solar nebula cannot produce non-mass dependent fractionation. In such a case the observed isotopic ratios characterise elements differently synthesised and injected into the solar nebula which condensed before it had enough time to homogenise. Thus the isotopically anomalous matter has extra solar origin and may contain supernovae condensates, interstellar matter or dust from other stars. The evidence for different isotopic anomalies is briefly summarised and discussed in terms of the current ideas regarding chemical processes occurring in the early solar system.


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