Thermo- and UV-responsive amphiphilic nanogels via reversible [4+4] photocycloaddition of PEG/PCL-based polyurethane dispersions

2021 ◽  
pp. 110800
Author(s):  
Lucas Polo Fonseca ◽  
Maria Isabel Felisberti
2015 ◽  
Vol 132 (42) ◽  
pp. n/a-n/a ◽  
Author(s):  
Magdalena Serkis ◽  
Rafał Poręba ◽  
Jiří Hodan ◽  
Jana Kredatusová ◽  
Milena Špírková

2018 ◽  
Vol 58 (12) ◽  
pp. 1338-1346 ◽  
Author(s):  
Harshit Gupta ◽  
John Texter

2015 ◽  
Vol 7 (44) ◽  
pp. 24641-24648 ◽  
Author(s):  
Laura Breucker ◽  
Katharina Landfester ◽  
Andreas Taden

2012 ◽  
Vol 126 (S2) ◽  
pp. E275-E282 ◽  
Author(s):  
Da-Kong Lee ◽  
Hong-Bing Tsai ◽  
Zong-Da Yang ◽  
Ruey-Shi Tsai

2021 ◽  
Vol 2 (6 (110)) ◽  
pp. 21-29
Author(s):  
Yevhenii Levchenko ◽  
Olga Sverdlikovska ◽  
Denys Chervakov ◽  
Oleh Chervakov

This paper reports the synthesis of ionic liquids through the interaction between diethanolamine and orthophosphate and boric acids in order to establish the possibility of replacing volatile coalescents in a formulation for paints and varnishes with ionogenic compounds. The results from studying the influence of polymeric coalescents based on ionic liquids on the rheological properties of water-dispersion paints and varnishes of different nature are presented. It has been established that the synthesized coalescents could be used to modify the properties of paints and varnishes based on polyurethane and styrene-acrylic aqueous dispersions. It has been shown that the product of the interaction between diethanolamine and boric acid in aqueous solutions forms an ionogenic complex compound with a unipolar conductivity in terms of ОН─ ions. It was also established that when introduced to the formulation of water-dispersion paints and varnishes, the solutions of modifiers produce a diluting action. The influence of ionic liquids on the process of film formation of aqueous dispersions of polymers and pigmented paints and varnishes based on them was investigated. It was established that the synthesized ionogenic compounds are not inferior, in terms of their effectiveness, to the widespread conventional industrial coalescents of the Texanol→ type. Therefore, there is reason to assert the possibility of replacing the industrial coalescent Texanol→ in the formulation of pigmented water-dispersion paints and varnishes based on styrene-acrylic and polyurethane dispersions with fundamentally new synthesized ionogenic modifiers. Thus, the coatings with a coalescent based on ion liquid of diethanolamine borate have a higher level of conditional hardness, which exceeds by 17 % the hardness index of the paint made on the basis of the conventional Texanol→ type coalescent, without changing its decorative properties, such as color and shine


2018 ◽  
Vol 101 ◽  
pp. 324-331 ◽  
Author(s):  
I. Jiménez-Pardo ◽  
P. Sun ◽  
R.A.T.M. van Benthem ◽  
A.C.C. Esteves

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