Liquid-liquid equilibrium in binary and ternary mixtures containing formaldehyde, water, methanol, methylal, and poly(oxymethylene) dimethyl ethers

2016 ◽  
Vol 425 ◽  
pp. 127-135 ◽  
Author(s):  
Niklas Schmitz ◽  
Anne Friebel ◽  
Erik von Harbou ◽  
Jakob Burger ◽  
Hans Hasse
Keyword(s):  
Ternary Mixtures ◽  
Liquid Equilibrium ◽  
Binary And Ternary Mixtures

Properties of Refrigerants from Cubic Equations of State

2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Viorel Feroiu ◽  
Dan Geana ◽  
Catinca Secuianu
Keyword(s):  
Experimental Data ◽  
Vapor Pressure ◽  
Equations Of State ◽  
Ternary Mixtures ◽  
Volumetric Properties ◽  
Mixing Rules ◽  
Saturation Curve ◽  
Equilibrium Thermodynamic ◽  
Liquid Equilibrium ◽  
Binary And Ternary Mixtures

Vapour � liquid equilibrium, thermodynamic and volumetric properties were predicted for three pure hydrofluorocarbons: difluoromethane (R32), pentafluoroethane (R125) and 1,1,1,2 � tetrafluoroethane (R134a) as well as for binary and ternary mixtures of these refrigerants. Three cubic equations of state GEOS3C, SRK (Soave � Redlich � Kwong) and PR (Peng � Robinson) were used. A wide comparison with literature experimental data was made. For the refrigerant mixtures, classical van der Waals mixing rules without interaction parameters were used. The GEOS3C equation, with three parameters estimated by matching several points on the saturation curve (vapor pressure and corresponding liquid volumes), compares favorably to other equations in literature, being simple enough for applications.

Vapor-liquid equilibrium simulation of binary and ternary mixtures of CH4, C2H4 and iso-C4H10

2014 ◽  
Vol 20 (2) ◽  
pp. 79-85
Author(s):  
Lühong Zhang ◽  
Jing Zhang ◽  
Yongli Sun ◽  
Jiao Yan ◽  
Yuhua Liu ◽  
...  
Keyword(s):  
Ternary Mixtures ◽  
Liquid Equilibrium ◽  
Vapor Liquid Equilibrium ◽  
Binary And Ternary Mixtures ◽  
Equilibrium Simulation ◽  
Vapor Liquid

scholarly journals Kelvin’s Dissymmetric Models and Consistency Conditions of Multicomponent Gas-Liquid Equilibrium and Capillary Condensation

2016 ◽  
Vol 2016 ◽  
pp. 1-21
Author(s):  
Mikhail Panfilov ◽  
Alexandre Koldoba
Keyword(s):  
Mathematical Theory ◽  
Equations Of State ◽  
Capillary Condensation ◽  
Ternary Mixtures ◽  
Chemical Components ◽  
Liquid Equilibrium ◽  
Suggested Approach ◽  
New Approach ◽  
Binary And Ternary Mixtures ◽  
Multicomponent Gas

To describe phase equilibrium of mixtures, we develop a nonclassical approach based on using different equations of state for gas and liquid. We show that not all the types of EOS are admissible but only those which verify some specific conditions of consistency. We developed the mathematical theory of this new approach for pure cores and for mixtures, in presence and absence of capillary forces, which leads to explicit analytical relationships for phase concentrations of chemical components. Several examples of comparison with experimental data for binary and ternary mixtures illustrate the feasibility of the suggested approach.

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