Liquid-State Volumetric Properties of a Set of Alcohols with Up to Five Carbon Atoms

This work provides density data (~1300 values) of 14 alcohols with up to five carbon atoms at p ∈ [0.1–40] MPa and T ∈ [278–358] K. The information obtained is modeled with a convenient reformulation of the Tait equation from which the volumetric coefficients, α and β, are derived both analytically and numerically. The general EoS containing α and β is also used for checking the consistency of the hypothesis on the invariability of the cited thermophysic parameters. The results obtained can be considered reliable because of the low estimated errors between the experimental data and those of the literature, which are below 0.4% for volume, while for the volumetric coefficients there is always a reference diverging 10%, or less, from the proposed model estimations. By including the averages of α and β into the general state of equation the errors increase, being <15%, compared to those based on the Tait equation. Hence, the assumption on the stability of the volumetric coefficients in this working interval is sufficient to make rough estimations of the molar volume of the selected alcohols.

Stability and Volumetric Properties of Colored Asphalt Mixtures Containing Iron Oxide

The objective of this paper is find the effect of using iron oxide as a filler on the Marshall stability, flow and the volumetric properties of HMA and compared the results with conventional HMA using limestone dust. Three blends were used: coarse, mid and fine with neat bitumen (AC 40-50). One aggregate type (crushed) with two types of fillers: limestone and iron oxide III (α- ) with three different filler content 6%, 8% and 10%. The Marshall mix design was conducted on the three blends and the optimum binder content is computed for each blend. The Marshall stability test results and the volumetric properties analysis showed that increasing the iron oxide content from 6% to 10% increases the stability about 28%, 17% , 16% for the coarse , mid and fine mixtures respectively. This increment in stability of mixtures using iron oxide related to the increment in specific gravity of the mix (Gmb) by (1.3% to 1.5% about 30 to 50 kg/m3). On the other hand, the flow of mixtures is decreased about (5%) for mixes using iron oxide than the ones that used limestone as filler. The fine blend with 10% iron oxide exhibit the highest stability of 13.3 kN. While the coarse blend stability was 10 kN for the same filler type and content. Generally, the Marshall Test results of HMA using iron oxide as filler showed better resistance to plastic deformation, also produce denser HMA with higher stiffness. On the other hand, the volumetric properties analysis showed lesser values as compared with conventional mixture where the void in mineral aggregates and void filled with asphalt has decreased but within the acceptable limits.

Balanced Mix Design Benchmarking of Field-Produced Asphalt Mixtures in Maine, U.S.

Performance testing has been recognized by state highway agencies (SHAs) in the U.S. and the asphalt paving industry as an important tool to complement volumetric properties for improving asphalt pavement performance. Thus, Maine Department of Transportation (MaineDOT) initiated a research effort in 2019 to evaluate the cracking and rutting resistance of asphalt mixtures using several performance tests, including the Hamburg wheel-tracking test (HWTT), indirect tensile cracking test (IDEAL-CT), cyclic fatigue test, and stress sweep rutting (SSR) test. These tests were conducted on reheated common plant-produced asphalt mixtures, and results were analyzed to: (1) develop baseline rutting and cracking performance; (2) evaluate the effects of mixture properties on the performance test results; and (3) verify the performance enhancement from the extended use of polymer-modified asphalt binders. Several mixture properties, such as nominal maximum aggregate size (NMAS), binder performance grade (PG), binder content (Pb), and reclaimed asphalt pavement (RAP) %, were found to have statistically significant effects on the mixture rutting and cracking resistance, especially the HWTT and IDEAL-CT results. Based on the proposed criteria for rutting strain index (RSI) and apparent damage capacity (Sapp), the asphalt mixtures tested would provide satisfactory rutting performance under heavy traffic, and satisfactory cracking performance under standard traffic. In addition, based on the IDEAL-CT benchmarking results, mixtures with polymer-modified binder and/or smaller NMAS were found to have higher cracking tolerance index (CTindex) results. The information from the research effort will help MaineDOT to achieve its goal to move beyond sole use of volumetric properties for asphalt mixture design and acceptance with the implementation of balanced mix design (BMD) for improving the field performance of asphalt pavements.

The linear thermal expansion coefficient of Inconel 617 alloy

The experimental results of a study of the thermal expansion of Inconel 617 alloy in the temperature range of 293.15-1460 K are presented. An anomalous change in the thermal expansion coefficient at high temperatures was detected. The initial data are obtained with an error within 3%. The approximation equations and the table of reference values for the temperature dependence of the volumetric properties are obtained.

Volumetric Properties for the Aqueous Solution of Yttrium Trichloride at Temperatures from 283.15 to 363.15 K and Ambient Pressure

To effectively develop the rare earth elements resources from the geothermal waters, it is essential to understand the volumetric properties of the aqueous solution system to establish the relative thermodynamic model. In this study, densities of YCl3 (aq) at the molalities of 0.08837–1.60639 mol·kg−1 from 283.15 K to 363.15 K at 5 K intervals and ambient pressure were measured experimentally by an Anton Paar digital vibrating-tube densimeter. Based on experimental data, the volumetric properties including apparent molar volume (Vϕ) and the coefficient of thermal expansion of the solution (α) of the binary systems (YCl3 + H2O) were derived. The 3D diagram (mi, T, Vϕ) of apparent molar volumes against temperature and molality was plotted. On the basis of the Pitzer ion-interaction model of electrolyte, the Pitzer single-salt parameters ( β MX 0 v , β MX 1 v , and C MX v ) for YCl3 and temperature-dependence equation F(i, p, T) = a1 + a2ln(T/298.15) + a3(T-298.15) + a4/(620-T) + a5(T-227) as well as their coefficients ai (i = 1–5) in the binary system were obtained for the first time. The values of Pitzer single-salt parameters of YCl3 agree well with the calculated values corresponding to the temperature-dependence equations, indicating that single-salt parameters and temperature-dependent formula obtained in this work are reliable.