Synthesis, X-ray characterization and DFT study of a novel Fe(III)–pyridine-2,6-dicarboxylic acid N-oxide complex with unusual coordination mode

Encouraged by the successful syntheses of alloy nanoclusters (or nanoparticles) via intercluster (or interparticle) reactions, herein we apply this methodology to prepare a series of bimetallic hydride clusters. Mixing of...

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Crystal structures of (S)- and (R,S)-2,2′-bipyridine-3,3′-dicarboxylic acid 1,1′-dioxides and of their barium salts: absolute configuration and molecular distortion enforced by supramolecular self-assembly

Zeitschrift für Kristallographie - Crystalline Materials ◽

10.1524/zkri.1997.212.3.226 ◽

1997 ◽

Vol 212 (3) ◽

Cited By ~ 7

Author(s):

P. Vojtíšek ◽

I. Císařová ◽

J. Podlaha ◽

Z. Žák ◽

S. Böhm ◽

...

Keyword(s):

Single Crystal ◽

Dicarboxylic Acid ◽

Crystal Structures ◽

Absolute Configuration ◽

Self Assembly ◽

Barium Salt ◽

X Ray Diffraction ◽

X Ray

AbstractCrystal structures of the title compounds were determined by single crystal X-ray diffraction. Absolute configuration of the barium salt of (+)-(

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Synthesis, X-ray structure, spectroscopic and DFT study of cis-[Ru(PPh3)(L)X2] complexes (X=Cl−, Br−, I− and NCS−) (L=1-methyl-2-{(o-thiomethyl)phenylazo}imidazole)

Inorganica Chimica Acta ◽

10.1016/j.ica.2012.09.011 ◽

2013 ◽

Vol 394 ◽

pp. 583-590 ◽

Cited By ~ 11

Author(s):

Mahendra Sekhar Jana ◽

Ajoy Kumar Pramanik ◽

Subhankar Kundu ◽

Deblina Sarkar ◽

Subrata Jana ◽

...

Keyword(s):

Dft Study ◽

X Ray

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[Zn(phen)2(CX3COO)]+, X = H orCl; Influence of X on the Coordination Mode of the Carboxylate Group (phen = 1,10-Phenanthroline)

Zeitschrift für Naturforschung B ◽

10.1515/znb-2005-1005 ◽

2005 ◽

Vol 60 (10) ◽

pp. 1049-1053 ◽

Cited By ~ 1

Author(s):

Zeanab Talaei ◽

Ali Morsali ◽

Ali R. Mahjoub

Keyword(s):

Nmr Spectroscopy ◽

Elemental Analysis ◽

Coordination Mode ◽

Bidentate Ligand ◽

Carboxylate Group ◽

X Ray ◽

X Ray Crystallography ◽

H Nmr ◽

Coordinate Geometry ◽

C Nmr

Two new ZnII(phen)2 complexes with trichloroacetate and acetate anions, [Zn(phen)2(CCl3COO)- (H2O)](ClO4) and [Zn(phen)2(CH3COO)](ClO4), have been synthesized and characterized by elemental analysis, IR, 1H NMR, 13C NMR spectroscopy. The single crystal X-ray data of these compounds show the Zn atoms to have six-coordinate geometry. From IR spectra and X-ray crystallography it is established that the coordination of the COO− group is different for trichloroacetate and acetate. The former acts as a monodentate whereas the latter acts as a bidentate ligand.

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