Sulfur functionality-modified starches: Review of synthesis strategies, properties, and applications

Author(s):  
Mehdi Jaymand
Keyword(s):  
Author(s):  
Sarah Silva ◽  
Luciana Amorim ◽  
Karine Nóbrega ◽  
Hélio Lira ◽  
Juliano Magalhães

Chemistry ◽  
2021 ◽  
Vol 3 (2) ◽  
pp. 658-671
Author(s):  
Paola Alzate ◽  
Lía Gerschenson ◽  
Silvia Flores

Ultrasound technique was used to produce native and acetylated cassava starch particles containing potassium sorbate (KS). In order to obtain an active packaging, films with addition of native starch particles containing KS (NKSPF) or added with acetylated starch particles containing KS (AKSPF) were formulated. As control systems, films without KS (CF) or added with KS that was not retained in particles (KSF), were produced. The NKSPF and AKSPF microstructure was consistent with composite materials. Tensile test revealed that CF and KSF were ductile and extensible (stress at break (σb) 2.8–2.5 MPa and strain at break (εb) 284–206%), while NKSPF and AKSPF were more resistant films with higher Young’s Modulus (148–477 MPa) and σb (3.6–17 MPa) but lower εb (40–11%). Moreover, NKSPF and AKSPF developed lower Yellowness Index (6.6–6.5) but higher opacity (19–23%) and solubility in water (31–35%) than KSF (9, 10.8% and 9%, respectively). It was observed that KSF and NKSPF moderately reduced the Zygosaccharomyces bailii growth while AKSPF showed the highest yeast inhibition, three Log-cycles, compared to CF. Additionally, FTIR spectroscopy revealed intensified interactions between KS and modified starch. It was concluded that starch sonication and acetylation were useful modifications to produce particles carrier of KS that improved the physical and antimicrobial performance of active films.


2009 ◽  
Vol 52 (3) ◽  
pp. 701-713 ◽  
Author(s):  
Luciana Shizue Matsuguma ◽  
Luiz Gustavo Lacerda ◽  
Egon Schnitzler ◽  
Marco Aurélio da Silva Carvalho Filho ◽  
Célia Maria Landi Franco ◽  
...  

Two commercial varieties of Peruvian carrot ('Amarela de Carandaí' and 'Senador Amaral') were processed into flour, starch and bagasse and chemically evaluated. The starch was extracted, modified with H2O2 and characterized by the physicochemical methods. By using the methylene blue dyeing, the granules of the modified starches showed intense blue color. The carboxyl content, the reducing power and the amount of the water liberated from the pastes after the freeze-thawing were higher for the oxidized starches and their pastes were clearer than those of the native starches of the two varieties from the two production areas. The RVA viscoamylography showed that the modified starches had lower viscosities with differences between the varieties. In the thermal analysis, the temperatures of the pyrolysis were higher for the native (310.37, 299.08, 311.18 ºC) than for the modified starches (294.16, 296.65 e 293.29 ºC) for both the varieties. This difference could be related with the larger surface of the granules due to the partial degradation promoted by the chemical modification. In almost all results, the differences were evident between the varieties but not for the cultivation places.


1986 ◽  
Vol 6 (6) ◽  
pp. 443-462 ◽  
Author(s):  
Richard Helm ◽  
Raymond A. Young ◽  
Roger McPherson ◽  
Robert Klem

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