Hydrogen production by steam-gasification of carbonaceous materials using concentrated solar energy—IV. Reactor experimentation with vacuum residue

2008 ◽  
Vol 33 (2) ◽  
pp. 679-684 ◽  
Author(s):  
A ZGRAGGEN
Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 462
Author(s):  
Houssame Boujjat ◽  
Sylvain Rodat ◽  
Stéphane Abanades

Solar biomass gasification is an attractive pathway to promote biomass valorization while chemically storing intermittent solar energy into solar fuels. The economic feasibility of a solar gasification process at a large scale for centralized H2 production was assessed, based on the discounted cash-flow rate of return method to calculate the minimum H2 production cost. H2 production costs from solar-only, hybrid and conventional autothermal biomass gasification were evaluated under various economic scenarios. Considering a biomass reference cost of 0.1 €/kg, and a land cost of 12.9 €/m2, H2 minimum price was estimated at 2.99 €/kgH2 and 2.48 €/kgH2 for the allothermal and hybrid processes, respectively, against 2.25 €/kgH2 in the conventional process. A sensitivity study showed that a 50% reduction in the heliostats and solar tower costs, combined with a lower land cost of below 0.5 €/m2, allowed reaching an area of competitiveness where the three processes meet. Furthermore, an increase in the biomass feedstock cost by a factor of 2 to 3 significantly undermined the profitability of the autothermal process, in favor of solar hybrid and solar-only gasification. A comparative study involving other solar and non-solar processes led to conclude on the profitability of fossil-based processes. However, reduced CO2 emissions from the solar process and the application of carbon credits are definitely in favor of solar gasification economics, which could become more competitive. The massive deployment of concentrated solar energy across the world in the coming years can significantly reduce the cost of the solar materials and components (heliostats), and thus further alleviate the financial cost of solar gasification.


2012 ◽  
Vol 512-515 ◽  
pp. 1418-1421 ◽  
Author(s):  
Qiu Hui Yan ◽  
Bei Bei Wang

Based on the integration of different systems and the comprehensive step utilization of energy, the system of hydrogen production by biomass gasification in supercritical water using concentrated solar energy has been coupled by using the combination of solar and biomass as an energy source. As a model compound of biomass, glucose was gasified in supercritical water at 25MPa and 873K, whether there is pre-heater water in the hydrogen production system was compared by the way of thermodynamic analysis. The results show that energy and exergy efficiency is high in the hydrogen production system with pre-heat water.


2019 ◽  
Vol 3 (3) ◽  
pp. 63 ◽  
Author(s):  
ABANADES

Solar thermochemical processes have the potential to efficiently convert high-temperature solar heat into storable and transportable chemical fuels such as hydrogen. In such processes, the thermal energy required for the endothermic reaction is supplied by concentrated solar energy and the hydrogen production routes differ as a function of the feedstock resource. While hydrogen production should still rely on carbonaceous feedstocks in a transition period, thermochemical water-splitting using metal oxide redox reactions is considered to date as one of the most attractive methods in the long-term to produce renewable H2 for direct use in fuel cells or further conversion to synthetic liquid hydrocarbon fuels. The two-step redox cycles generally consist of the endothermic solar thermal reduction of a metal oxide releasing oxygen with concentrated solar energy used as the high-temperature heat source for providing reaction enthalpy; and the exothermic oxidation of the reduced oxide with H2O to generate H2. This approach requires the development of redox-active and thermally-stable oxide materials able to split water with both high fuel productivities and chemical conversion rates. The main relevant two-step metal oxide systems are commonly based on volatile (ZnO/Zn, SnO2/SnO) and non-volatile redox pairs (Fe3O4/FeO, ferrites, CeO2/CeO2−, perovskites). These promising hydrogen production cycles are described by providing an overview of the best performing redox systems, with special focus on their capabilities to produce solar hydrogen with high yields, rapid reaction rates, and thermochemical performance stability, and on the solar reactor technologies developed to operate the solid–gas reaction systems.


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