Coupling of copper–chloride hybrid thermochemical water splitting cycle with a desalination plant for hydrogen production from nuclear energy

2010 ◽  
Vol 35 (4) ◽  
pp. 1560-1574 ◽  
Author(s):  
Mehmet F. Orhan ◽  
Ibrahim Dincer ◽  
Greg F. Naterer ◽  
Marc A. Rosen
Author(s):  
Roxanne Garland ◽  
Sara Dillich ◽  
Eric Miller ◽  
Kristine Babick ◽  
Kenneth Weil

The goal of the US Department of Energy (DOE) hydrogen production portfolio is to research and develop low-cost, highly efficient and environmentally friendly production technologies based on diverse, domestic resources. The DOE Hydrogen Program integrates basic and applied research, as well as technology development and demonstration, to adequately address a diverse range of technologies and feedstocks. The program encompasses a broad spectrum of coordinated activities within the DOE Offices of Energy Efficiency and Renewable Energy (EERE), Nuclear Energy (NE), Fossil Energy (FE), and Science (SC). Hydrogen can be produced in small, medium, and larger scale facilities, with small-scale distributed facilities producing from 100 to 1,500 kilograms (kg) of hydrogen per day at fueling stations, and medium-scale (also known as semi-central or city-gate) facilities producing from 1,500 to 50,000 kg per day on the outskirts of cities. The largest central facilities would produce more than 50,000 kg of hydrogen per day. Specific technologies currently under program development for distributed hydrogen production include bio-derived renewable liquids and water electrolysis. Centralized renewable production pathways under development include water electrolysis integrated with renewable power (e.g., wind, solar, hydroelectric, or geothermal), biomass gasification, solar-driven high-temperature thermochemical water splitting, direct photoelectrochemical water splitting, and biological production methods using algal/bacterial processes. To facilitate commercialization of hydrogen production via these various technology pathways in the near and long terms, a “Hydrogen Production Roadmap” has been developed which identifies the key challenges and high-priority research and development needs associated with each technology. The aim is to foster research that will lead to hydrogen production with near-zero net greenhouse gas emissions, using renewable energy sources, nuclear energy, and/or coal (with carbon capture and storage). This paper describes the research and development needs and activities by various DOE offices to address the key challenges in the portfolio of hydrogen production technologies.


2004 ◽  
Author(s):  
R. Buckingham ◽  
B. Russ ◽  
L. Brown ◽  
G.E. Besenbruch ◽  
F. Gelbard ◽  
...  

Author(s):  
Luthfi L. Lubis ◽  
Ibrahim Dincer ◽  
Marc A. Rosen

A life cycle assessment (LCA) of nuclear-based hydrogen production using thermochemical water splitting is conducted. The copper-chlorine thermochemical cycle is considered, and the environmental impacts of the nuclear and thermochemical plants are assessed. Environmental impacts are investigated using CML-2001 impact categories. The nuclear plant and the construction of the hydrogen plant contribute significantly to the total environmental impacts. The environmental impacts of operating the hydrogen production plant contribute much less. Changes in the inventory of materials or chemicals needed in the thermochemical plant do not affect significantly the total impacts. Improvement analysis suggests the development of more sustainable processes, particularly in the nuclear plant and construction of the hydrogen production plant.


2010 ◽  
Vol 132 (2) ◽  
Author(s):  
L. L. Lubis ◽  
I. Dincer ◽  
M. A. Rosen

A life cycle assessment of nuclear-based hydrogen production using thermochemical water splitting is conducted. The copper-chlorine thermochemical cycle is considered, and the environmental impacts of the nuclear and thermochemical plants are assessed. Environmental impacts are investigated using CML-2001 impact categories. The nuclear plant and the construction of the hydrogen plant contribute significantly to the total environmental impacts. The environmental impacts of operating the hydrogen production plant contribute much less. Changes in the inventory of materials or chemicals needed in the thermochemical plant do not affect significantly the total impacts. Improvement analysis suggests the development of more sustainable processes, particularly in the nuclear plant and construction of the hydrogen production plant.


2020 ◽  
Vol 16 ◽  
Author(s):  
Yuxue Wei ◽  
Honglin Qin ◽  
Jinxin Deng ◽  
Xiaomeng Cheng ◽  
Mengdie Cai ◽  
...  

Introduction: Solar-driven photocatalytic hydrogen production from water splitting is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. In this review, recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. In particular, the factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Background: Photocatalytic hydrogen evolution from water splitting using photocatalyst semiconductors is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. Methods: This review summarizes the recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation. Results: Recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. The factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Conclusion: The state-of-the-art CdS for producing hydrogen from photocatalytic water splitting under visible light is discussed. The future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are also described.


Nanoscale ◽  
2021 ◽  
Author(s):  
Dongxue Yao ◽  
Lingling Gu ◽  
Bin Zuo ◽  
Shuo Weng ◽  
Shengwei Deng ◽  
...  

The technology of electrolyzing water to prepare high-purity hydrogen is an important field in today's energy development. However, how to prepare efficient, stable, and inexpensive hydrogen production technology from electrolyzed...


2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Shan Wang ◽  
Aolin Lu ◽  
Chuan-Jian Zhong

AbstractAs a promising substitute for fossil fuels, hydrogen has emerged as a clean and renewable energy. A key challenge is the efficient production of hydrogen to meet the commercial-scale demand of hydrogen. Water splitting electrolysis is a promising pathway to achieve the efficient hydrogen production in terms of energy conversion and storage in which catalysis or electrocatalysis plays a critical role. The development of active, stable, and low-cost catalysts or electrocatalysts is an essential prerequisite for achieving the desired electrocatalytic hydrogen production from water splitting for practical use, which constitutes the central focus of this review. It will start with an introduction of the water splitting performance evaluation of various electrocatalysts in terms of activity, stability, and efficiency. This will be followed by outlining current knowledge on the two half-cell reactions, hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), in terms of reaction mechanisms in alkaline and acidic media. Recent advances in the design and preparation of nanostructured noble-metal and non-noble metal-based electrocatalysts will be discussed. New strategies and insights in exploring the synergistic structure, morphology, composition, and active sites of the nanostructured electrocatalysts for increasing the electrocatalytic activity and stability in HER and OER will be highlighted. Finally, future challenges and perspectives in the design of active and robust electrocatalysts for HER and OER towards efficient production of hydrogen from water splitting electrolysis will also be outlined.


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