Solid-state amorphization in a Ti2Pd intermetallic compound under fast-electron irradiation

2013 ◽  
Vol 581 ◽  
pp. 324-329 ◽  
Author(s):  
Satoshi Anada ◽  
Takeshi Nagase ◽  
Hidehiro Yasuda ◽  
Hirotaro Mori
2021 ◽  
Vol 1016 ◽  
pp. 990-996
Author(s):  
Takeshi Nagase

Fast electron irradiation can induce the solid-state amorphization (SSA) of many intermetallic compounds. The occurrence of SSA stimulated by fast electron irradiation was found in the Al0.5TiZrPdCuNi high-entropy alloy (HEA). The relationship between the occurrence of SSA in intermetallic compounds under fast electron irradiation and the empirical alloy parameters for predicting the solid-solution-formation tendency in HEAs was discussed. The occurrence of SSA in intermetallic compounds was hardly predicted, only by the alloy parameters of δ or ΔHmix, which have been widely used for predicting solid-solution formation in HEAs. All intermetallic compounds with ΔHmix ≤ -35 kJ/mol and those with δ ≥ 12.5 exhibit the occurrence of SSA. This implies that the intermetallic compounds with a largely negative ΔHmix value and a largely positive δ parameter are favorable for the occurrence of SSA.


2011 ◽  
Vol 19 (4) ◽  
pp. 511-517 ◽  
Author(s):  
Takeshi Nagase ◽  
Kazuya Takizawa ◽  
Yukichi Umakoshi

2014 ◽  
Vol 71 ◽  
pp. 195-205 ◽  
Author(s):  
Satoshi Anada ◽  
Takeshi Nagase ◽  
Keita Kobayashi ◽  
Hidehiro Yasuda ◽  
Hirotaro Mori

Author(s):  
D.E. Luzzi

When certain intermetallic compounds are irradiated with ballistic electrons at low temperatures, the crystal becomes unstable and transforms into an amorphous phase. This electron irradiation induced crystalline to amorphous (C-A) transition is one of a recently discovered class of amorphization processes which occur in the solid state [1]. The relative simplicity of electron-matter interactions, and the ability to follow the transition inside the microscope, make the electron induced C-A transition ideal for the study of these amorphization processes.A bright field image sequence which depicts several features of the C-A transition is shown in the figure. In this example, CuTim was irradiated with 2 MeV electrons at 191 K (9.2 x 1023 e/m2-s; 5.5 x 10-3 dpa/s). The arrows mark a fixed position. In the images, taken after different irradiation times (a:30s, b:60s c:300s), the transition is evident from the distortion of the bend contour around the irradiated area.


2010 ◽  
Vol 18 (4) ◽  
pp. 441-450 ◽  
Author(s):  
Takeshi Nagase ◽  
Kazuya Takizawa ◽  
Makoto Wakeda ◽  
Yoji Shibutani ◽  
Yukichi Umakoshi

2013 ◽  
Vol 62 (3) ◽  
pp. 185-190 ◽  
Author(s):  
Takeshi NAGASE ◽  
Atsushi SASAKI ◽  
Kazuya TAKIZAWA ◽  
Hiroyuki YASUDA ◽  
Tomoyuki TERAI ◽  
...  

1991 ◽  
Vol 6 (10) ◽  
pp. 2059-2068 ◽  
Author(s):  
D.E. Luzzi

Evidence of directional structural disordering prior to complete amorphization of Cu4Ti3 during 2 MeV electron irradiation is presented. It is shown that the observed disordering is intrinsic to the irradiated material and is incommensurate with the structure of the crystalline compound. The results point to the presence of significant anisotropy in the response of the material to irradiation. A model based on local rotation of clusters of atoms within a partially chemically-disordered matrix is developed. These results are discussed in relation to recent proposed mechanisms of amorphization based on volume expansion. The questions raised by this work indicate a need for detailed studies of the atomic level structural evolution of a material during solid state amorphization.


2011 ◽  
Vol 19 (9) ◽  
pp. 1313-1318 ◽  
Author(s):  
Takeshi Nagase ◽  
Atsushi Sasaki ◽  
Hiroyuki Y. Yasuda ◽  
Hirotaro Mori ◽  
Tomoyuki Terai ◽  
...  

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