Environmentally friendly epoxidation of olefins under phase-transfer catalysis conditions with hydrogen peroxide

2007 ◽  
Vol 249 (2) ◽  
pp. 338-348 ◽  
Author(s):  
Y MAHHA ◽  
L SALLES ◽  
J PIQUEMAL ◽  
E BRIOT ◽  
A ATLAMSANI ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Environmentally Friendly ◽  
Epoxidation Of Olefins

scholarly journals Epoxidation of 1,5,9-cyclododecatriene with hydrogen peroxide under phase-transfer catalysis conditions: influence of selected parameters on the course of epoxidation

2021 ◽  
Vol 132 (2) ◽  
pp. 983-1001
Author(s):  
Grzegorz Lewandowski ◽  
Marcin Kujbida ◽  
Agnieszka Wróblewska
Keyword(s):  
Hydrogen Peroxide ◽  
Reaction Time ◽  
Catalytic System ◽  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Environmentally Friendly ◽  
Molar Ratio ◽  
Oxidizing Agent ◽  
Catalyst Content

AbstractThis work presents the studies on the epoxidation of 1,5,9-cyclododecatriene (CDT) with hydrogen peroxide as the oxidizing agent, under conditions of the phase transfer catalysis (PTC), and with the following catalytic system: H2WO4/H3PO4/[CH3(CH2)7]3CH3N+HSO4− (compounds were mixed at the ratio of 2:1:1). The influence of the following parameters on the course of this process was investigated: catalyst content, molar ratio of H2O2:CDT, temperature and type of solvent. The highest yield of 1,2-epoxy-5,9-cyclododecadiene (ECDD) (54.9 mol%), at the conversion of CDT reached 72.3 mol%, was obtained at the temperature of 50 °C, for the catalyst content of 0.45 mol% (in relation to the introduced CDT), for the molar ratio of H2O2:CDT 1.5:1, with toluene as the solvent and after the reaction time of 30 min. Considering the he obtained results and numerous applications of ECDD, further research should be developed to provide a more efficient and environmentally friendly way of obtaining this compound. Graphic abstract

Efficiency of phase-transfer catalysis in cyclopentene epoxidation with hydrogen peroxide

2012 ◽  
Vol 85 (4) ◽  
pp. 661-665 ◽  
Author(s):  
A. E. Meshechkina ◽  
L. V. Mel’nik ◽  
G. V. Rybina ◽  
S. S. Srednev ◽  
A. S. Shevchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Phase Transfer Catalysis ◽  
Phase Transfer

scholarly journals Electrosynthesis of Hydrogen Peroxide by Phase-Transfer Catalysis

Joule ◽  
2019 ◽  
Vol 3 (12) ◽  
pp. 2942-2954 ◽  
Author(s):  
Alexander T. Murray ◽  
Sahag Voskian ◽  
Marcel Schreier ◽  
T. Alan Hatton ◽  
Yogesh Surendranath
Keyword(s):  
Hydrogen Peroxide ◽  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Electrosynthesis Of Hydrogen Peroxide
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