Highly efficient and selective reduction of nitroarenes into anilines catalyzed by gold nanoparticles incarcerated in a nanoporous polymer matrix: Role of the polymeric support and insight into the reaction mechanism

2016 ◽  
Vol 340 ◽  
pp. 30-40 ◽  
Author(s):  
Annarita Noschese ◽  
Antonio Buonerba ◽  
Patrizia Canton ◽  
Stefano Milione ◽  
Carmine Capacchione ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Reaction Mechanism ◽  
Polymer Matrix ◽  
Selective Reduction ◽  
Polymeric Support ◽  
Highly Efficient ◽  
Insight Into

On the role of gold nanoparticles in the selective photooxidation of 2-propanol over Au/TiO2

2015 ◽  
Vol 17 (16) ◽  
pp. 10391-10397 ◽  
Author(s):  
Alexander Lüken ◽  
Martin Muhler ◽  
Jennifer Strunk
Keyword(s):  
Gold Nanoparticles ◽  
Electron Transfer ◽  
Reaction Mechanism ◽  
Conduction Band ◽  
Electron Acceptor ◽  
Au Nanoparticles ◽  
Hole Capture ◽  
Insight Into

Partial insight into the reaction mechanism of the photooxidation of 2-propanol over Au/TiO2. 2-Propanol is activated by hole capture and converted to acetone requiring the presence of O2 as an electron acceptor. The deposited Au nanoparticles are assumed to facilitate the electron transfer from the TiO2 conduction band to adsorbed O2.

New Insight into the Role of Gold Nanoparticles in Au@CdS Core-Shell Nanostructures for Hydrogen Evolution

Small ◽  
2014 ◽  
Vol 10 (22) ◽  
pp. 4664-4670 ◽  
Author(s):  
Xiang Ma ◽  
Kun Zhao ◽  
Hongjie Tang ◽  
Ying Chen ◽  
Chenguang Lu ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Hydrogen Evolution ◽  
Core Shell ◽  
Shell Nanostructures ◽  
Insight Into

scholarly journals Insight into the role of selenization time for highly efficient Mn doped Cu2ZnSn(S,Se)4 thin film based solar cells

2022 ◽  
Vol 8 ◽  
pp. 37-44
Author(s):  
Zhanwu Wang ◽  
Wenjie He ◽  
Meiling Ma ◽  
Yingrui Sui
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Highly Efficient ◽  
Mn Doped ◽  
Insight Into

Identifying the role of process conditions for synthesis of stable gold nanoparticles and insight detail of reaction mechanism

2021 ◽  
pp. 1-14
Author(s):  
Muhammad Irfan ◽  
Muhammad Moniruzzaman ◽  
Tausif Ahmad ◽  
Mohamad Fakhrul Ridhwan Samsudin ◽  
Farzana Bashir ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Reaction Mechanism ◽  
Process Conditions

Enantioselective Reduction Reactions Using Chiral Ionic Liquids: An Overview

2018 ◽  
Vol 15 (5) ◽  
pp. 578-586 ◽  
Author(s):  
Avtar Singh ◽  
Nirmaljeet Kaur ◽  
Harish Kumar Chopra
Keyword(s):  
Ionic Liquids ◽  
Reaction Mechanism ◽  
Reaction Medium ◽  
Reduction Reaction ◽  
Additional Benefit ◽  
Reduction Reactions ◽  
Chiral Ionic Liquids ◽  
Enantioselective Reduction ◽  
Insight Into

Background: Enantioselective reduction reactions play a key role to synthesize compounds of industrial importance. A number of metal and biocatalysts have been developed for their use in this reaction. Chiral ionic liquids (CILs) have been widely used as the reaction medium and the organocatalysts in enantioselective reduction reactions. Objective: This paper focuses on the systematic literature review about the use of chiral ionic liquids (CILs) in the enantioselective reduction reaction. The mechanistic aspects of these species are also taken into account. Conclusion: This review concludes that a number of chiral ionic liquids (CILs) have been successfully employed as the organocatalysts and the reaction medium in the enantioselective reduction reactions. The review also gives an insight into the role of these species in the reaction mechanism. For most of the reactions, chiral ionic liquids provide promising results in terms of yield and enantioselectivity. The recyclability of these chiral moieties from the reaction mixtures offers an additional benefit for the use of these species in asymmetric reactions.

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