scholarly journals Modelling the precipitation of nanoparticles in a closed medium in the presence of seeds: Application to amorphous silica synthesis.

Author(s):  
C. Noguera ◽  
B. Fritz ◽  
A. Clément ◽  
D. Lemarchand
2016 ◽  
Vol 4 (2) ◽  
pp. 2278-2290 ◽  
Author(s):  
Gabriel M. Faé Gomes ◽  
Caterina Philipssen ◽  
Eduardo K. Bard ◽  
Leandro Dalla Zen ◽  
Guilherme de Souza

Author(s):  
J. W. Mellowes ◽  
C. M. Chun ◽  
I. A. Aksay

Mullite (3Al2O32SiO2) can be fabricated by transient viscous sintering using composite particles which consist of inner cores of a-alumina and outer coatings of amorphous silica. Powder compacts prepared with these particles are sintered to almost full density at relatively low temperatures (~1300°C) and converted to dense, fine-grained mullite at higher temperatures (>1500°C) by reaction between the alumina core and the silica coating. In order to achieve complete mullitization, optimal conditions for coating alumina particles with amorphous silica must be achieved. Formation of amorphous silica can occur in solution (homogeneous nucleation) or on the surface of alumina (heterogeneous nucleation) depending on the degree of supersaturation of the solvent in which the particles are immersed. Successful coating of silica on alumina occurs when heterogeneous nucleation is promoted and homogeneous nucleation is suppressed. Therefore, one key to successful coating is an understanding of the factors such as pH and concentration that control silica nucleation in aqueous solutions. In the current work, we use TEM to determine the optimal conditions of this processing.


In many rice producing countries of the world, including in Vietnam, various research aimed at using rice husk ash (RHA) as a finely dispersed active mineral additive in cements, concrete and mortars are being conducted. The effect of the duration of the mechanoactivation of the RHA, produced under laboratory conditions in Vietnam, on its pozzolanic activity were investigated in this study. The composition of ash was investigated by laser granulometry and the values of indicators characterizing the dispersion of its particles before and after mechanical activation were established. The content of soluble amorphous silicon oxide in rice husk ash samples was determined by photocolorimetric analysis. The pizzolanic activity of the RHA, fly ash and the silica fume was also compared according to the method of absorption of the solution of the active mineral additive. It is established that the duration of the mechanical activation of rice husk ash by grinding in a vibratory mill is optimal for increasing its pozzolanic activity, since it simultaneously results in the production of the most dispersed ash particles with the highest specific surface area and maximum solubility of the amorphous silica contained in it. Longer grinding does not lead to further reduction in the size of ash particles, which can be explained by their aggregation, and also reduces the solubility of amorphous silica in an aqueous alkaline medium.


RSC Advances ◽  
2021 ◽  
Vol 11 (15) ◽  
pp. 8927-8939
Author(s):  
Laura Fiameni ◽  
Ahmad Assi ◽  
Ario Fahimi ◽  
Bruno Valentim ◽  
Karen Moreira ◽  
...  

Rice husk poultry litter ash (RHPLA) is proposed as a valuable secondary source to recover phopshorus and amorphous silica in three steps.


Author(s):  
Steven A. Yamada ◽  
Samantha T. Hung ◽  
Jae Yoon Shin ◽  
Michael D. Fayer

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