The reductive leaching of waste lithium ion batteries in presence of iron ions: Process optimization and kinetics modelling

2020 ◽  
Vol 262 ◽  
pp. 121312 ◽  
Author(s):  
Sina Ghassa ◽  
Akbar Farzanegan ◽  
Mahdi Gharabaghi ◽  
Hadi Abdollahi
Keyword(s):  
Lithium Ion Batteries ◽  
Process Optimization ◽  
Lithium Ion ◽  
Iron Ions ◽  
Kinetics Modelling ◽  
Reductive Leaching

scholarly journals Recovery of Co, Li, and Ni from Spent Li-Ion Batteries by the Inorganic and/or Organic Reducer Assisted Leaching Method

Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 555 ◽  
Author(s):  
Weronika Urbańska
Keyword(s):  
Sulfuric Acid ◽  
Lithium Ion Batteries ◽  
Laboratory Experiments ◽  
Glutaric Acid ◽  
Lithium Ion ◽  
Reducing Agent ◽  
Li Ion Batteries ◽  
Reductive Leaching ◽  
Li Ion ◽  
H2o2 Solution

The battery powder (anodic and cathodic mass) manually separated from spent Li-ion batteries used in laptops was subjected to acidic reductive leaching to recover the Co, Li, and Ni contained in it. In the laboratory experiments, 1.5 M sulfuric acid was used as the leaching agent and the reducing agents were 30% H2O2 solution or/and glutaric acid. Glutaric acid is a potential new reducing agent in the leaching process of spent lithium-ion batteries (LIBs). The influence of the type of the used reducer on obtained recovery degrees of Co, Li, and Ni as well as the synergism of the two tested reducing compounds were analyzed. As a result, it was determined that it is possible to efficiently hydrometallurgically separate Co, Li, and Ni from battery powder into solutions. The highest recovery degrees of the investigated metals (Co: 87.85%; Li: 99.91%; Ni: 91.46%) were obtained for samples where two reducers, perhydrol and glutaric acid, were added, thus confirming the assumed synergic action of H2O2 and C5H8O4 in a given reaction environment.

scholarly journals Hydrometallurgical recycling of lithium-ion batteries by reductive leaching with sodium metabisulphite

2018 ◽  
Vol 71 ◽  
pp. 350-361 ◽  
Author(s):  
Nathália Vieceli ◽  
Carlos A. Nogueira ◽  
Carlos Guimarães ◽  
Manuel F.C. Pereira ◽  
Fernando O. Durão ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Sodium Metabisulphite ◽  
Reductive Leaching

scholarly journals Biomass-Assisted Reductive Leaching in H2SO4 Medium for the Recovery of Valuable Metals from Spent Mixed-Type Lithium-Ion Batteries

JOM ◽  
2019 ◽  
Vol 71 (12) ◽  
pp. 4465-4472 ◽  
Author(s):  
Yongming Chen ◽  
Di Chang ◽  
Nannan Liu ◽  
Fang Hu ◽  
Chao Peng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Mixed Type ◽  
Lithium Ion ◽  
Biomass Waste ◽  
Solid Ratio ◽  
Secondary Use ◽  
Reductive Leaching ◽  
Waste Tea ◽  
Biomass Dosage ◽  
Hydrometallurgical Method

Abstract A hydrometallurgical method involving natural biomass waste as reductant was proposed for the treatment of spent mixed-type lithium-ion batteries. Results showed that almost complete dissolution of Li, Ni, Mn and nearly 90% dissolution of Co were achieved under the optimal conditions of H2SO4 concentration of 2 M, waste tea biomass dosage of 0.3 g/g, solid/ratio of 50 g L−1, temperature of 90°C and time of 120 min. The leaching kinetics was further investigated, and the activation energies were determined to be 1.7 kJ mol−1, 10.3 kJ mol−1, 10.1 kJ mol−1 and 10.9 kJ mol−1 for Li, Ni, Mn and Co, respectively. The cathode materials before leaching and the leaching residue were characterized with different analytical methods. The characterization results confirmed that the addition of the waste tea acted as reductant and resulted in better dissolution of the metals, supporting the principles of sustainable processes by decreasing the chemical consumption and integrating waste into a secondary use.

CuS2 sheets: a hidden anode material with a high capacity for sodium-ion batteries

2021 ◽  
Author(s):  
Shaohua Lu ◽  
Weidong Hu ◽  
Xiaojun Hu
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Low Cost ◽  
High Capacity ◽  
Lithium Ion ◽  
Sodium Ion ◽  
Sodium Ion Batteries

Due to their low cost and improved safety compared to lithium-ion batteries, sodium-ion batteries have attracted worldwide attention in recent decades.

Synthesis and study of carbon nanostructured additives for lithium-ion batteries

2018 ◽  
Vol 125 (4) ◽  
pp. 8-13
Author(s):  
А.Б. Абдрахманова ◽  
◽  
В. А. Кривченко ◽  
Н. М. Омарова
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion
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