Highly efficient Ni/ZrO2 catalysts prepared via combustion method for CO2 methanation

2016 ◽  
Vol 16 ◽  
pp. 236-244 ◽  
Author(s):  
Kechao Zhao ◽  
Weihan Wang ◽  
Zhenhua Li
2018 ◽  
Vol 10 (19) ◽  
pp. 16352-16357 ◽  
Author(s):  
Hamidreza Arandiyan ◽  
Yuan Wang ◽  
Jason Scott ◽  
Sara Mesgari ◽  
Hongxing Dai ◽  
...  

2018 ◽  
Vol 26 (11) ◽  
pp. 2361-2367 ◽  
Author(s):  
Yuexiu Jiang ◽  
Tongxia Huang ◽  
Lihui Dong ◽  
Zuzeng Qin ◽  
Hongbing Ji

Fuel ◽  
2014 ◽  
Vol 137 ◽  
pp. 155-163 ◽  
Author(s):  
Yan Zeng ◽  
Hongfang Ma ◽  
Haitao Zhang ◽  
Weiyong Ying ◽  
Dingye Fang

2016 ◽  
Vol 6 (13) ◽  
pp. 4777-4785 ◽  
Author(s):  
Lei Shi ◽  
Dong Sun ◽  
Yuxin Wang ◽  
Yisheng Tan ◽  
Jie Li ◽  
...  

Metallic Cu/ZnO catalysts were directly prepared by a formic acid-assisted solid-state combustion method without further reduction.


Catalysts ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 523 ◽  
Author(s):  
Luhui Wang ◽  
Junang Hu ◽  
Hui Liu ◽  
Qinhong Wei ◽  
Dandan Gong ◽  
...  

Mesoporous Ni-based catalysts with Ni confined in nanochannels are widely used in CO2 methanation. However, when Ni loadings are high, the nanochannels are easily blocked by nickel particles, which reduces the catalytic performance. In this work, three-dimensional mesoporous Ni-CeO2-CSC catalysts with high Ni loadings (20−80 wt %) were prepared using a colloidal solution combustion method, and characterized by nitrogen adsorption–desorption, X-ray diffraction (XRD), transmission electron microscopy (TEM) and H2 temperature programmed reduction (H2-TPR). Among the catalysts with different Ni loadings, the 50% Ni-CeO2-CSC with 50 wt % Ni loading exhibited the best catalytic performance in CO2 methanation. Furthermore, the 50% Ni-CeO2-CSC catalyst was stable for 50 h at 300° and 350 °C in CO2 methanation. The characterization results illustrate that the 50% Ni-CeO2-CSC catalyst has Ni particles smaller than 5 nm embedded in the pore walls, and the Ni particles interact with CeO2. On the contrary, the 50% Ni-CeO2-CP catalyst, prepared using the traditional coprecipitation method, is less active and selective for CO2 methanation due to the larger size of the Ni and CeO2 particles. The special three-dimensional mesoporous embedded structure in the 50% Ni-CeO2-CSC can provide more metal–oxide interface and stabilize small Ni particles in pore walls, which makes the catalyst more active and stable in CO2 methanation.


Catalysts ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 442 ◽  
Author(s):  
Guoli Tang ◽  
Dandan Gong ◽  
Hui Liu ◽  
Luhui Wang

Highly dispersed Ni-based catalysts for CO2 methanation have been extensively studied over the last decade. However, a highly loaded Ni-based catalyst always results in a large Ni particle size and poor CO2 methanation activity. In this work, a colloidal solution combustion method was used to prepare a highly loaded Ni–La2O3 catalyst (50 wt % Ni) with a small Ni particle size and abundant metal–support interface. The characterizations demonstrated that a Ni–La2O3 catalyst prepared in this way has a mesoporous structure and a small Ni particle size. Due to the small Ni particle size and abundant metal–support interface, the highly loaded mesoporous Ni–La2O3 catalyst exhibits higher activity and selectivity in CO2 methanation compared to the Ni–La2O3 catalyst prepared by a conventional solution combustion method.


2018 ◽  
Vol 24 (5) ◽  
pp. 471-479 ◽  
Author(s):  
Zhenhua Li ◽  
Lijuan Zhang ◽  
Kechao Zhao ◽  
Li Bian

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