BGO/AlFu MOF core shell nano-composite based bromide ion-selective electrode

2020 ◽  
Vol 8 (5) ◽  
pp. 104375 ◽  
Author(s):  
Navjot Kaur ◽  
Jagseer Kaur ◽  
Rahul Badru ◽  
Sandeep Kaushal ◽  
Prit Pal Singh
1976 ◽  
Vol 59 (1) ◽  
pp. 53-55
Author(s):  
James E Graf ◽  
Troy E Vaughn ◽  
William H Kipp

Abstract The use of the bromide ion selective electrode for the determination of bromide ion in wine has been found to be rapid and reliable. The method has been used for still wines and carbonated wines and is applicable to all wines regardless of their country of origin. The method consists of treating a 50 ml aliquot of wine with 2 ml each of 3.75M H3PO4, saturated KNO3, and 1M CuSO4. After 10 min the electrodes are immersed in the samples and a millivolt reading is obtained. One hundred μl 500 ppm bromide ion standard is added and the millivolt reading is taken. Bromide ion concentration in the wine = (CΔ × 1)/((antilog ΔE/S) − 1) where CΔ = 1, ΔE = the change in potential expressed in millivolts, and S = the electrode slope.


2016 ◽  
Vol 21 (1) ◽  
pp. 76-81 ◽  
Author(s):  
Armila Rajbhandari Nyachhyon ◽  
Krishna Manandhar ◽  
Raja Ram Pradhananga

Bromide ion selective electrode (Br-ISE) have been successfully fabricated in the laboratory. The polycrystalline Ag2S-AgBr membrane material of Br-ISE was prepared by co-precipitation of silver sulphide and silver bromide from aqueous solution and was characterized by X-ray diffractometry (XRD). XRD results showed that material is in mixed phase state having Ag3SBr, Ag2S and AgBr. Scanning electron microscopy (SEM) has been used to study the texture of the surface. The potentiometric response has been investigated by 2 electrode system whereas 3 electrode systems have been used for electrochemical impedance spectroscopy (EIS). The electrode was found to behave well up to the bromide concentration of 1x10-5M with a Nernstian slope of 58 mV per decade change in bromide ion concentration. The selectivity coefficient of electrode containing bromide ion in the presence of I- and Cl- ions was found to be 3.98 and 8x10-2, respectively indicating that I- and Cl- ions interfere in the response of bromide electrode to bromide ion. The EIS studies shows that the charge transfer process is the key mechanism that is going on at the electrode/ electrolyte interface and electrode/ back contact interface.Journal of Institute of Science and TechnologyVol. 21, No. 1, 2016, page: 76-81


1986 ◽  
Vol 69 (1) ◽  
pp. 67-69
Author(s):  
Ezzat M Abdel-Moety ◽  
Abdel-Kader S Ahmad ◽  
Mohie Sharaf El-Din

Abstract A semimicro method for determination of iodine values of lipids is described. An accurately weighed smear of sample (10-20 mg) on a strip of ashless filter paper, 14 × 40 mm, is brominated with bromine vapors for about 5 min. Excess bromine adsorbed on the filter paper is allowed to sublime. Bromine absorbed by the sample is directly related to the degree of unsaturation. Paper with brominated sample is subjected to oxygen flask combustion in the presence of 2 mL 1M sodium hydroxide solution and 10 mL water as absorbing liquid. Bromide formed, which is equivalent to unsaturation, is determined by bromide ion selective electrode. Bromide ions can be also determined by gravimetry or by indirect argentometric titration. The results were statistically analyzed. The iodine values of some fatty acids and oils, determined by this technique, are in accord with those of some officially approved methods.


1976 ◽  
Vol 9 (9) ◽  
pp. 795-805 ◽  
Author(s):  
Paul K. C. Tseng ◽  
W. F. Gutknecht

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