Heterovalent Zr4+-Cu2+ substitution in zirconium pyrophosphate: From theoretical models to synthesis and utilization

Over the past several years, it has become increasingly evident that materials for proposed advanced energy systems will be required to operate at high temperatures and in aggressive environments. These constraints make structural ceramics attractive materials for these systems. However it is well known that the condition of the specimen surface of ceramic materials is often critical in controlling properties such as fracture toughness, oxidation resistance, and wear resistance. Ion implantation techniques offer the potential of overcoming some of the surface related limitations.While the effects of implantation on surface sensitive properties may be measured indpendently, it is important to understand the microstructural evolution leading to these changes. Analytical electron microscopy provides a useful tool for characterizing the microstructures produced in terms of solute concentration profiles, second phase formation, lattice damage, crystallinity of the implanted layer, and annealing behavior. Such analyses allow correlations to be made with theoretical models, property measurements, and results of complimentary techniques.

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On the Relationship Between General Auditory Sensitivity and Speech Perception: An Examination of Pitch and Lexical Tone Perception in 4- to 6-Year-Old Children

Journal of Speech Language and Hearing Research ◽

10.1044/2019_jslhr-19-00104 ◽

2020 ◽

Vol 63 (2) ◽

pp. 487-498

Author(s):

Puisan Wong ◽

Man Wai Cheng

Keyword(s):

Speech Perception ◽

Theoretical Models ◽

Developmental Trajectory ◽

Auditory Sensitivity ◽

Pitch Discrimination ◽

Lexical Tone ◽

Perceptual Training ◽

Lexical Tones ◽

Tone Perception ◽

Tone Discrimination

Purpose Theoretical models and substantial research have proposed that general auditory sensitivity is a developmental foundation for speech perception and language acquisition. Nonetheless, controversies exist about the effectiveness of general auditory training in improving speech and language skills. This research investigated the relationships among general auditory sensitivity, phonemic speech perception, and word-level speech perception via the examination of pitch and lexical tone perception in children. Method Forty-eight typically developing 4- to 6-year-old Cantonese-speaking children were tested on the discrimination of the pitch patterns of lexical tones in synthetic stimuli, discrimination of naturally produced lexical tones, and identification of lexical tone in familiar words. Results The findings revealed that accurate lexical tone discrimination and identification did not necessarily entail the accurate discrimination of nonlinguistic stimuli that followed the pitch levels and pitch shapes of lexical tones. Although pitch discrimination and tone discrimination abilities were strongly correlated, accuracy in pitch discrimination was lower than that in tone discrimination, and nonspeech pitch discrimination ability did not precede linguistic tone discrimination in the developmental trajectory. Conclusions Contradicting the theoretical models, the findings of this study suggest that general auditory sensitivity and speech perception may not be causally or hierarchically related. The finding that accuracy in pitch discrimination is lower than that in tone discrimination suggests that comparable nonlinguistic auditory perceptual ability may not be necessary for accurate speech perception and language learning. The results cast doubt on the use of nonlinguistic auditory perceptual training to improve children's speech, language, and literacy abilities.

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Positive Arousal Enhances the Consolidation of Item Memory

Swiss Journal of Psychology ◽

10.1024/1421-0185/a000151 ◽

2015 ◽

Vol 74 (2) ◽

pp. 91-104 ◽

Cited By ~ 1

Author(s):

Bo Wang

Keyword(s):

Episodic Memory ◽

Memory Consolidation ◽

Source Memory ◽

Emotional Arousal ◽

Theoretical Models ◽

Memory Test ◽

Learning Phase ◽

Item Memory ◽

Memory Tests ◽

Immediate Memory

Emotional arousal induced after learning has been shown to modulate memory consolidation. However, it is unclear whether the effect of postlearning arousal can extend to different aspects of memory. This study examined the effect of postlearning positive arousal on both item memory and source memory. Participants learned a list of neutral words and took an immediate memory test. Then they watched a positive or a neutral videoclip and took delayed memory tests after either 25 minutes or 1 week had elapsed after the learning phase. In both delay conditions, positive arousal enhanced consolidation of item memory as measured by overall recognition. Furthermore, positive arousal enhanced consolidation of familiarity but not recollection. However, positive arousal appeared to have no effect on consolidation of source memory. These findings have implications for building theoretical models of the effect of emotional arousal on consolidation of episodic memory and for applying postlearning emotional arousal as a technique of memory intervention.

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The Role of Distress Disclosure Tendencies in the Experience and Expression of Laboratory-Induced Sadness

Journal of Individual Differences ◽

10.1027/1614-0001/a000222 ◽

2017 ◽

Vol 38 (1) ◽

pp. 55-62 ◽

Cited By ~ 1

Author(s):

Jeffrey H. Kahn ◽

Daniel W. Cox ◽

A. Myfanwy Bakker ◽

Julia I. O’Loughlin ◽

Agnieszka M. Kotlarczyk

Keyword(s):

Individual Differences ◽

Emotional Reactivity ◽

Subjective Experience ◽

Negative Emotion ◽

Theoretical Models ◽

Laboratory Research ◽

Emotion Words ◽

Distress Disclosure ◽

Computerized Text Analysis

Abstract. The benefits of talking with others about unpleasant emotions have been thoroughly investigated, but individual differences in distress disclosure tendencies have not been adequately integrated within theoretical models of emotion. The purpose of this laboratory research was to determine whether distress disclosure tendencies stem from differences in emotional reactivity or differences in emotion regulation. After completing measures of distress disclosure tendencies, social desirability, and positive and negative affect, 84 participants (74% women) were video recorded while viewing a sadness-inducing film clip. Participants completed post-film measures of affect and were then interviewed about their reactions to the film; these interviews were audio recorded for later coding and computerized text analysis. Distress disclosure tendencies were not predictive of the subjective experience of emotion, but they were positively related to facial expressions of sadness and happiness. Distress disclosure tendencies also predicted judges’ ratings of the verbal disclosure of emotion during the interview, but self-reported disclosure and use of positive and negative emotion words were not associated with distress disclosure tendencies. The authors present implications of this research for integrating individual differences in distress disclosure with models of emotion.

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Convergent and Predictive Validity of Implicit and Explicit Anxiety Measures as a Function of Specificity Similarity and Content Similarity

European Journal of Psychological Assessment ◽

10.1027/1015-5759.24.4.254 ◽

2008 ◽

Vol 24 (4) ◽

pp. 254-262 ◽

Cited By ~ 15

Author(s):

Tobias Gschwendner ◽

Wilhelm Hofmann ◽

Manfred Schmitt

Keyword(s):

Implicit Association Test ◽

Theoretical Models ◽

Implicit Measures ◽

Speech Anxiety ◽

Behavioral Indicators ◽

General Anxiety ◽

Anxious Behavior ◽

Content Similarity ◽

Implicit And Explicit ◽

Validation Strategy

In the present study we applied a validation strategy for implicit measures like the IAT, which complements multitrait-multimethod (MTMM) analyses. As the measurement method (implicit vs. explicit) and underlying representation format (associative vs. propositional) are often confounded, the validation of implicit measures has to go beyond MTMM analysis and requires substantive theoretical models. In the present study (N = 133), we employed such a model ( Hofmann, Gschwendner, Nosek, & Schmitt, 2005 ) and investigated two moderator constructs in the realm of anxiety: specificity similarity and content similarity. In the first session, different general and specific anxiety measures were administered, among them an Implicit Association Test (IAT) general anxiety, an IAT-spider anxiety, and an IAT that assesses speech anxiety. In the second session, participants had to deliver a speech and behavioral indicators of speech anxiety were measured. Results showed that (a) implicit and explicit anxiety measures correlated significantly only on the same specification level and if they measured the same content, and (b) specific anxiety measures best predicted concrete anxious behavior. These results are discussed regarding the validation of implicit measures.

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Does CBT for Psychosis Have an Impact on Delusions by Improving Reasoning Biases and Negative Self-Schemas?

Zeitschrift für Psychologie ◽

10.1027/2151-2604/a000335 ◽

2018 ◽

Vol 226 (3) ◽

pp. 152-163 ◽

Cited By ~ 2

Author(s):

Stephanie Mehl ◽

Björn Schlier ◽

Tania M. Lincoln

Keyword(s):

Behavioral Therapy ◽

Theoretical Models ◽

Self Esteem ◽

Secondary Outcome ◽

Intervention Effect ◽

Produce Change ◽

Attribution Biases ◽

Carry Over ◽

Implicit And Explicit ◽

Reasoning Biases

Abstract. Cognitive-behavioral therapy for psychosis (CBTp) builds on theoretical models that postulate reasoning biases and negative self-schemas to be involved in the formation and maintenance of delusions. However, it is unclear whether CBTp induces change in delusions by improving these proposed causal mechanisms. This study reports on a mediation analysis of a CBTp effectiveness trial in which delusions were a secondary outcome. Patients with psychosis were randomized to individualized CBTp (n = 36) or a waiting list condition (WL; n = 34). Reasoning biases (jumping to conclusions, theory of mind, attribution biases) and self-schemas (implicit and explicit self-esteem; self-schemas related to different domains) were assessed pre- and post-therapy/WL. The results reveal an intervention effect on two of four measures of delusions and on implicit self-esteem. Nevertheless, the intervention effect on delusions was not mediated by implicit self-esteem. Changes in explicit self-schemas and reasoning biases did also not mediate the intervention effects on delusions. More focused interventions may be required to produce change in reasoning and self-schemas that have the potential to carry over to delusions.

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