Reactivity of α-trifluoromethanesulfonyl esters, amides and ketones: Decarboxylative allylation, methylation, and enol formation

2013 ◽  
Vol 153 ◽  
pp. 151-161 ◽  
Author(s):  
Han Il Kong ◽  
Monica A. Gill ◽  
Amy H. Hrdina ◽  
Jennifer E. Crichton ◽  
Jeffrey M. Manthorpe
Keyword(s):  
Decarboxylative Allylation ◽  
Enol Formation

ChemInform Abstract: Reactivity of α-Trifluoromethanesulfonyl Esters, Amides and Ketones: Decarboxylative Allylation, Methylation, and Enol Formation.

ChemInform ◽  
2014 ◽  
Vol 45 (17) ◽  
pp. no-no
Author(s):  
Han Il Kong ◽  
Monica A. Gill ◽  
Amy H. Hrdina ◽  
Jennifer E. Crichton ◽  
Jeffrey M. Manthorpe
Keyword(s):  
Decarboxylative Allylation ◽  
Enol Formation

Synthesis of fluorinated donepezil by palladium-catalyzed decarboxylative allylation of α-fluoro-β-keto ester with tri-substituted heterocyclic alkene and the self-disproportionation of its enantiomers

RSC Advances ◽  
2016 ◽  
Vol 6 (88) ◽  
pp. 85058-85062 ◽  
Author(s):  
Mayaka Maeno ◽  
Hiroya Kondo ◽  
Etsuko Tokunaga ◽  
Norio Shibata
Keyword(s):  
Alzheimer’S Disease ◽  
Alzheimer's Disease ◽  
Asymmetric Synthesis ◽  
Therapeutic Agent ◽  
The Self ◽  
Keto Ester ◽  
Catalytic Asymmetric Synthesis ◽  
Palladium Catalyzed ◽  
Catalytic Asymmetric ◽  
Decarboxylative Allylation

Catalytic asymmetric synthesis of fluorinated donepezil, a promising new therapeutic agent for Alzheimer's disease, was achieved.

Surface‐Driven Keto–Enol Tautomerization: Atomistic Insights into Enol Formation and Stabilization Mechanisms

2018 ◽  
Vol 130 (51) ◽  
pp. 16901-16906 ◽  
Author(s):  
Smadar Attia ◽  
Marvin‐Christopher Schmidt ◽  
Carsten Schröder ◽  
Pascal Pessier ◽  
Swetlana Schauermann
Keyword(s):  
Enol Formation

Iridium-catalyzed regioselective decarboxylative allylation of β-ketoacids: efficient construction of γ,δ-unsaturated ketones

2015 ◽  
Vol 51 (57) ◽  
pp. 11512-11514 ◽  
Author(s):  
Shu-Jie Chen ◽  
Guo-Ping Lu ◽  
Chun Cai
Keyword(s):  
Allylic Alcohols ◽  
Unsaturated Ketones ◽  
Efficient Construction ◽  
Decarboxylative Allylation

A highly regioselective protocol is reported for the efficient construction of γ,δ-unsaturated ketones from β-ketoacids and allylic alcohols.

ChemInform Abstract: Stereoselective β-C-Glycosylation by a Palladium-Catalyzed Decarboxylative Allylation: Formal Synthesis of Aspergillide A.

ChemInform ◽  
2013 ◽  
Vol 44 (40) ◽  
pp. no-no
Author(s):  
Jing Zeng ◽  
Jimei Ma ◽  
Shaohua Xiang ◽  
Shuting Cai ◽  
Xue-Wei Liu
Keyword(s):  
Formal Synthesis ◽  
Palladium Catalyzed ◽  
Decarboxylative Allylation

Silver‐Catalyzed Decarboxylative Allylation of Difluoroarylacetic Acids with Allyl Sulfones in Water

2020 ◽  
Vol 15 (7) ◽  
pp. 1175-1179 ◽  
Author(s):  
Xiang Li ◽  
Ruihong Zhang ◽  
Xiaofei Zhang ◽  
Peiyuan Zhu ◽  
Tuanli Yao
Keyword(s):  
Decarboxylative Allylation

Stereocontrolled O-Glycosylation with Palladium-Catalyzed Decarboxylative Allylation

2014 ◽  
Vol 79 (23) ◽  
pp. 11473-11482 ◽  
Author(s):  
Shaohua Xiang ◽  
Jingxi He ◽  
Yu Jia Tan ◽  
Xue-Wei Liu
Keyword(s):  
Palladium Catalyzed ◽  
Decarboxylative Allylation
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