Preparation, characterization, non-isothermal reaction kinetics, thermodynamic properties, and safety performances of high nitrogen compound: Hydrazine 3-nitro-1,2,4-triazol-5-one complex

2008 ◽  
Vol 153 (1-2) ◽  
pp. 261-268 ◽  
Author(s):  
Jian-hua Yi ◽  
Feng-qi Zhao ◽  
Hong-xu Gao ◽  
Si-yu Xu ◽  
Min-chang Wang ◽  
...  
1990 ◽  
Vol 10 (3) ◽  
pp. 293-310 ◽  
Author(s):  
Vincent L. Chiang ◽  
Jun Yu ◽  
Robert C. Eckert

RSC Advances ◽  
2016 ◽  
Vol 6 (11) ◽  
pp. 8892-8901 ◽  
Author(s):  
Himadri Sahu ◽  
Kaustubha Mohanty

In this work, waste fish bone was used as a source of natural hydroxyapatite which was later used for the preparation of a metal grafted catalyst.


2006 ◽  
Vol 31 (3) ◽  
pp. 163-168 ◽  
Author(s):  
Bryce C. Tappan ◽  
Arif N. Ali ◽  
Steven F. Son ◽  
Thomas B. Brill

2014 ◽  
Vol 87 (4) ◽  
pp. 617-628
Author(s):  
Min-Tzung Ye ◽  
Shinn-Gwo Hong

ABSTRACT The kinetics of the reaction between hexamethylene diisocyanate (HDI) and polypropylene glycols (PPG) of different molecular weights toward the synthesis of polyurethanes with versatile properties was studied using differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). From the dynamic exotherms observed in DSC, it was found that the Kissinger equation modified by an additional temperature term in its frequency factor term was able to accurately describe the isothermal reaction kinetics of all HDI/PPG reactions. The modification can be justified by analyses with the Ozawa method and the modulus observed under DMA measurements. Regardless of the type of PPG used, the frequency factors changed with respect to the degree of conversion and maximized at near 70% conversion. The derivation of the modified kinetic equation is presented. In addition, the empirical equations describing the dependence of the activation energies and frequency factors on the molecular weights of PPG were also derived.


1992 ◽  
Vol 203 ◽  
pp. 93-110 ◽  
Author(s):  
Ravindra K. Agrawal

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