Novel Foaming-Agent Free Insulating Geopolymer Based on Industrial Fly Ash and Rice Husk

This study highlights the synthesis of a new thermal insulating geopolymer based on the alkaline activation of fly ashes. A porous geopolymer material can be prepared without the addition of a foaming agent, using high ratio solution/ashes (activating solutions used are water, sodium or potassium hydroxide). In order to increase the porosity of the material and to make it more ecological, rice husks are incorporated into the formulation. The geopolymer materials were prepared at room temperature and dried at moderate temperature (105 °C) by a simple procedure. The microstructural characteristics of these new porous geopolymers were assessed by optical microscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA) and X-ray fluorescence (XRF). Infrared spectroscopy (FTIR) was used to confirm the geopolymerisation. The effect of the ratio solution/ashes and the percentage of the rice husk addition on thermal and mechanical analysis was evaluated. An insulating material for a solution/ashes ratio of 0.9 and a rice husk content of 15% having a λ value of 0.087 W/(m·K), a porosity of 61.4% and an Rc value of 0.1 MPa was successfully prepared.

Study on Mechanical Problems of Complex Rock Mass by Composite Material Micromechanics Methods: A Literature Review

The mechanical analysis of complex rock mass is a difficult problem, which often occurs in scientific research and practical engineering. Many achievements have been made in the study of rock mass composite problems by composite material micromechanics method, but it has not been well summarized so far. This paper summarizes in detail the research status of complex rock mass problems by composite material micromechanics method at home and abroad, including the application of the Eshelby equivalent inclusion theory and self-consistent model in rock mass composite problems, and the application of the homogenization method in jointed rock mass and other rock mass composite problems such as anchored rock mass, layered rock mass, and salt rock mass with impurities. It is proposed that the structural similarity and mechanical analysis similarity should be satisfied when the composite material micromechanics method is used to study the complex rock mass. Finally, the problems that need to be further studied are put forward. The research results provide a valuable reference for the study of complex rock mass by the composite material micromechanics method.

Mechanical and Thermomechanical Properties of Clay-Cowpea (Vigna Unguiculata Walp.) Husks Polyester Bio-Composite for Building Applications

This study investigates the feasibility of creating a clay polymer-based composite using cowpea husk (CPH) as filler for production of roof tiles. Polymeric composites were fabricated by mixing unsaturated polyester (UPT) resin with cowpea husk at different filler weights and curing. A hybrid composite was produced with the addition of 3 wt.% clay and all samples produced were subjected to flexural, hardness and dynamic mechanical analysis (DMA) tests. The effect of clay addition on the mechanical and thermo-mechanical behaviour of formulated composites was investigated. The morphological analysis of the mono and hybrid system shows a rough and coarse inhomogeneous surface with voids created due to the addition of CPH filler for the mono reinforced and clay uniformly filling the voids that were created by the CPH in the hybrid composite. It is observed that hardness, tensile modulus and flexural modulus of hybrid composites increase with an increase in the CPH contents, while the strength and flexural strength all decrease with filler content. The optimal composition was obtained using Grey relational analysis (GRA) at 18% CPH for both mono and hybrid composite. The results imply that the composite combination can be used in making rooftiles and/or also in applications where low strength is required.

Understanding the dielectric properties and electromagnetic shielding efficiency of zirconia filled epoxy-MWCNT composites

In the present study, hybrid composites are prepared by reinforcing various concentrations of high permittivity zirconia nanofiller into epoxy/CNT compositions to test their usability in EMI shielding applications in the X and Ku bands. ZrO2 nanofiller is added in different proportions to improve absorbance shielding while maintaining the composite conductivity uniform by adding constant CNT concentration to restrict the reflectance shielding. The microscopic studies have revealed an efficient dispersion of ZrO2 nanoparticles in the CNT networks and provided a smoother surface. The presence of zirconia nanofillers increased the dielectric properties, viz. the dielectric constant (194 at 0.1 Hz) and loss tangent (1.57 at 0.1 Hz), respectively, whereas the conductivity was found to be invariantly constant. The increased permittivity of composites enhanced the shielding by absorption, while the shielding by reflection is least influenced by the addition of zirconia nanofiller. The addition of zirconia nanofillers increased the permittivity and tan delta, allowing charges to accumulate at the interfacial areas for incoming EM radiations, resulting in increased absorbance shielding. Limiting the CNT concentration in all composites to the same level resulted in the formation of conductive networks, thus resulting in uniform reflectance shielding for all the hybrid composites in the present study. The dynamic mechanical analysis showed the improvement in the storage modulus and activation energy due to the enhanced interfacial adhesion and cross-linked polymer density.

Evaluation of Thermal Properties of Composites Prepared from Pistachio Shell Particles Treated Chemically and Polypropylene

The purpose of the present work was to prepare polypropylene (PP) matrix composited filled with chemically treated pistachio shell particles (PTx), and evaluate their effect on the composites’ thermal properties. PP-PTx composites were formulated in different PTx content (from 2 to 10 phr) in a mixing chamber, using the melt-mixing process. The PTx were chemically treated using a NaOH solution and infrared spectroscopy (FTIR). According to thermogravimetric analysis (TGA), the treatment of pistachio shell particles resulted in the remotion of lignin and hemicellulose. The thermal stability was evaluated by means of TGA, where the presence of PTx in composites showed a positive effect compared with PP pristine. Thermal properties such as crystallization temperature (Tc), crystallization enthalpy (∆Hc), melting temperature (Tm) and crystallinity were determinate by means differential scanning calorimetry (DSC); these results suggest that the PTx had a nucleation effect on the PP matrix, increasing their crystallinity. Dynamic mechanical analysis (DMA) showed that stiffness of the composites increase compared with that PP pristine, as well as the storage modulus, and the best results were found at a PTx concentration of 4 phr. At higher concentrations, the positive effect decreased; however, they were better than the reference PP.

Structure-dynamics relationships in cryogenically deformed bulk metallic glass

The atomistic mechanisms occurring during the processes of aging and rejuvenation in glassy materials involve very small structural rearrangements that are extremely difficult to capture experimentally. Here we use in-situ X-ray diffraction to investigate the structural rearrangements during annealing from 77 K up to the crystallization temperature in Cu44Zr44Al8Hf2Co2 bulk metallic glass rejuvenated by high pressure torsion performed at cryogenic temperatures and at room temperature. Using a measure of the configurational entropy calculated from the X-ray pair correlation function, the structural footprint of the deformation-induced rejuvenation in bulk metallic glass is revealed. With synchrotron radiation, temperature and time resolutions comparable to calorimetric experiments are possible. This opens hitherto unavailable experimental possibilities allowing to unambiguously correlate changes in atomic configuration and structure to calorimetrically observed signals and can attribute those to changes of the dynamic and vibrational relaxations (α-, β- and γ-transition) in glassy materials. The results suggest that the structural footprint of the β-transition is related to entropic relaxation with characteristics of a first-order transition. Dynamic mechanical analysis data shows that in the range of the β-transition, non-reversible structural rearrangements are preferentially activated. The low-temperature γ-transition is mostly triggering reversible deformations and shows a change of slope in the entropic footprint suggesting second-order characteristics.