Fabrication and modification of cellulose acetate based mixed matrix membrane: Gas separation and physical properties

A new polyhedral oligomeric silsesquioxane (POSS) designed with eight –(CH2)3–NH–(CH2)2–NH2 groups (PNEN) at its apexes was used as nanocomposite uploading into 1,2-bis(triethoxysilyl)ethane (BTESE)-derived organosilica to prepare mixed matrix membranes (MMMs) for gas separation. The mixtures of BTESE-PNEN were uniform with particle size of around 31 nm, which is larger than that of pure BTESE sols. The characterization of thermogravimetric (TG) and gas permeance indicates good thermal stability. A similar amine-contained material of 3-aminopropyltriethoxysilane (APTES) was doped into BTESE to prepare hybrid membranes through a copolymerized strategy as comparison. The pore size of the BTESE-PNEN membrane evaluated through a modified gas-translation model was larger than that of the BTESE-APTES hybrid membrane at the same concentration of additions, which resulted in different separation performance. The low values of Ep(CO2)-Ep(N2) and Ep(N2) for the BTESE-PNEN membrane at a low concentration of PNEN were close to those of copolymerized BTESE-APTES-related hybrid membranes, which illustrates a potential CO2 separation performance by using a mixed matrix membrane strategy with multiple amine POSS as particles.

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Investigation of cellulose acetate/gamma‐cyclodextrin MOF based mixed matrix membranes for CO 2 /CH 4 gas separation

Greenhouse Gases Science and Technology ◽

10.1002/ghg.2050 ◽

2021 ◽

Vol 11 (2) ◽

pp. 313-330

Author(s):

Ovaid Mehmood ◽

Sarah Farrukh ◽

Arshad Hussain ◽

Mohammad Younas ◽

Zarrar Salahuddin ◽

...

Keyword(s):

Cellulose Acetate ◽

Gas Separation ◽

Mixed Matrix Membranes ◽

Mixed Matrix ◽

Gamma Cyclodextrin ◽

Matrix Membranes

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Asymmetric mixed matrix membrane incorporating organically modified clay particle for gas separation

Chemical Engineering Journal ◽

10.1016/j.cej.2013.10.042 ◽

2014 ◽

Vol 241 ◽

pp. 495-503 ◽

Cited By ~ 50

Author(s):

A.K. Zulhairun ◽

A.F. Ismail ◽

T. Matsuura ◽

M.S. Abdullah ◽

A. Mustafa

Keyword(s):

Gas Separation ◽

Clay Particle ◽

Mixed Matrix Membrane ◽

Mixed Matrix ◽

Modified Clay ◽

Organically Modified

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Removal of Nickel by adsorption from Aqueous Solution of Cellulose Acetate-Zero Valent Iron Nanoparticle Mixed Matrix Membrane

Indian Journal of Science and Technology ◽

10.17485/ijst/2016/v9i41/99184 ◽

2016 ◽

Vol 9 (41) ◽

Author(s):

Aseem Ali Palliparambil ◽

Srilatha Bethireddy ◽

P. Hariprasad Reddy ◽

Satish Babu Rajulapati

Keyword(s):

Aqueous Solution ◽

Cellulose Acetate ◽

Zero Valent Iron ◽

Mixed Matrix Membrane ◽

Mixed Matrix ◽

Iron Nanoparticle

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Fe–Al–Mn@chitosan based metal oxides blended cellulose acetate mixed matrix membrane for fluoride decontamination from water: Removal mechanisms and antibacterial behavior

Journal of Membrane Science ◽

10.1016/j.memsci.2020.118372 ◽

2020 ◽

Vol 611 ◽

pp. 118372

Author(s):

Mohit Chaudhary ◽

Abhijit Maiti

Keyword(s):

Metal Oxides ◽

Cellulose Acetate ◽

Mixed Matrix Membrane ◽

Water Removal ◽

Mixed Matrix ◽

Removal Mechanisms

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A novel Co2+ exchanged zeolite Y/cellulose acetate mixed matrix membrane for CO2/N2 separation

Journal of the Taiwan Institute of Chemical Engineers ◽

10.1016/j.jtice.2015.10.042 ◽

2016 ◽

Vol 60 ◽

pp. 403-413 ◽

Cited By ~ 47

Author(s):

Hamidreza Sanaeepur ◽

Ali Kargari ◽

Bahram Nasernejad ◽

Abtin Ebadi Amooghin ◽

Mohammadreza Omidkhah

Keyword(s):

Cellulose Acetate ◽

Zeolite Y ◽

Mixed Matrix Membrane ◽

Mixed Matrix

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Mixed-matrix materials using metal–organic polyhedra with enhanced compatibility for membrane gas separation

Dalton Transactions ◽

10.1039/c8dt00082d ◽

2018 ◽

Vol 47 (24) ◽

pp. 7905-7915 ◽

Cited By ~ 22

Author(s):

Cressa Ria P. Fulong ◽

Junyi Liu ◽

Vincent J. Pastore ◽

Haiqing Lin ◽

Timothy R. Cook

Keyword(s):

Thin Films ◽

Gas Separation ◽

Polymer Thin Films ◽

Membrane Gas Separation ◽

Mixed Matrix ◽

Metal Organic

The dispersion of metal–organic polyhedra into polymer thin-films exploits the host/guest capabilities of the former and the processability of the latter.

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