Improving B1 field homogeneity in dielectric tube resonators for EPR spectroscopy via controlled shaping of the dielectric insert

2020 ◽  
Vol 311 ◽  
pp. 106685
Author(s):  
Victoria N. Syryamina ◽  
Anna G. Matveeva ◽  
Yan V. Vasiliev ◽  
Anton Savitsky ◽  
Yuri A. Grishin
2016 ◽  
Vol 10 (5) ◽  
pp. 186 ◽  
Author(s):  
Sidi Mohamed Ahmed Ghaly ◽  
Khalid. A. Al-snaie ◽  
Sulaiman S. Al-Sowayan

<p>In this paper, we present the design and testing of a radiofrequency prototype coil with good performances in terms of B<sub>1</sub> magnetic field homogeneity and can be utilized for Magnetic Resonance Imaging. It is constituted of four coaxial separately tuned rings of wire and symmetrically located on a spherical surface. Compared to standard Helmholtz pair, which has 2nd-order magnetic field homogeneity, it yields to improvement in field homogeneity, while preserving the simplicity of design. The four coils of proposed structure are tuned to the same frequency. The proposed structure gets at 4th-order magnetic field homogeneity by optimizing the distance between rings and the diameters of outer loops. An electrical modeling of the four-coil system taking into account the coupling effects between all rings permits to determine the resonance frequency in the homogenous mode. Measurements of B1 field homogeneity were introduced in free space. Compared to the Helmholtz coil, the proposed structure presents good performances in terms of B1 homogeneity, quality factor and sensitivity. The design of proposed coil has been optimized for best SNR performances. Globally, this work claims to be a contribution to the study of the four-coil RF systems derived from the Helmholtz pairs.</p>


1963 ◽  
Vol 36 (3_4) ◽  
pp. 247-248
Author(s):  
H. Dreeskamp
Keyword(s):  

1980 ◽  
Vol 45 (6) ◽  
pp. 1669-1676 ◽  
Author(s):  
Pavel Kubáček

The first step of electrochemical oxidation of 2-phenyl- and 2-(4-tolyl)-1,3,4,7-tetramethylisoindoles in anhydrous acetonitrile produces relatively stable cationradicals which have been studied by means of EPR spectroscopy using the method of internal electrochemical generation of radicals under reduced temperature. The same electrochemical behaviour of the both studied derivatives and identical EPR spectra of their cationradicals can be explained within the Huckel MO method. The largest contribution to the magnitude of splitting constant of nitrogen nucleus is due to π-σ-spin polarization of C-N bonds caused by high spin abundance of pz-AO of carbon atoms. Half-life of decomposition of the studied cationradicals is 4 min at -30°C.


1999 ◽  
Vol 64 (1) ◽  
pp. 149-156 ◽  
Author(s):  
Gabriel Čík ◽  
František Šeršeň ◽  
Alena Bumbálová

The formation of reactive oxygen species due to irradiation by a visible light of the polythiophene deposited in ZSM-5 zeolite channels in aqueous medium has been studied. Polymerization of thiophene was carried out in zeolite channels after the ion-exchange reaction of Na+ for Fe3+. By means of EPR spectroscopy, the temporarily generated 1O2 in irradiated aqueous medium was proved. The formation of O2-• was confirmed by the reduction of Fe3+-cytochrome c. Irradiation led to the water reduction to hydrogen.


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