High sensitivity of the anomalies in the rotational and ro-vibrational bands of carbon monoxide to small changes in the molecular potential and dipole moment

2018 ◽  
Vol 349 ◽  
pp. 60-63 ◽  
Author(s):  
Emile S. Medvedev ◽  
Vladimir G. Ushakov
2021 ◽  
Vol 21 (8) ◽  
pp. 4400-4405
Author(s):  
Junyeop Lee ◽  
Nam Gon Do ◽  
Dong Hyuk Jeong ◽  
Sae-Wan Kim ◽  
Maeum Han ◽  
...  

Carbon monoxide (CO) is an odorless, colorless, tasteless, extremely flammable, and highly toxic gas. It is produced when there is insufficient oxygen supply during the combustion of carbon to produce carbon dioxide (CO2). CO is produced from operating engines, stoves, or furnaces. CO poisoning occurs when CO accumulates in the bloodstream and can result in severe tissue damage or even death. Many types of CO sensors have been reported, including electrochemical, semiconductor metal-oxide, catalytic combustion, thermal conductivity, and infrared absorption-type for the detection of CO. However, despite their excellent selectivity and sensitivity, issues such as complexity, power consumption, and calibration limit their applications. In this study, a fabricbased colorimetric CO sensor is proposed to address these issues. Potassium disulfitopalladate (II) (K2Pd(SO3)2) is dyed on a polyester fabric as a sensing material for selective CO detection. The sensing characteristics and performance are investigated using optical instruments such as RGB sensor and spectrometer. The sensor shows immediate color change when exposed to CO at a concentration that is even lower than 20 ppm before 2 min. The fast response time of the sensor is attributed to its high porosity to react with CO. This easy-to-fabricate and cost-effective sensor can detect and prevent the leakage of CO simultaneously with high sensitivity and selectivity toward CO.


RSC Advances ◽  
2015 ◽  
Vol 5 (81) ◽  
pp. 65668-65673 ◽  
Author(s):  
Jun-Chao Ding ◽  
Hua-Yao Li ◽  
Ze-Xing Cai ◽  
Xiao-Dong Zhang ◽  
Xin Guo

LaCoO3-based sensors, as fabricated by LaCoO3 nanoparticles of ∼82 nm, show a response of ∼279.86 toward CO at 500 °C, due to the high content of O22−/O− species in LaCoO3.


1976 ◽  
Vol 54 (3) ◽  
pp. 258-261 ◽  
Author(s):  
Nina J. Fisher ◽  
F. W. Dalby

The electric dipole moments of the B1Σ+, C1Σ+, and A1Π states of the CO molecule have been determined by observing Stark effects on the Ångstrom and Herzberg bands. We find the excited B and C states to have dipole moments of (1.60 ± 0.15) and (4.52 ± 0.35) D respectively. The upper limit for the dipole moment of the A1Π state is (0.15 ± 0.05) D.


ChemInform ◽  
2010 ◽  
Vol 22 (36) ◽  
pp. no-no
Author(s):  
G. E. SCUSERIA ◽  
M. D. MILLER ◽  
F. JENSEN ◽  
J. GEERTSEN

2010 ◽  
Vol 93 (3) ◽  
pp. 742-749 ◽  
Author(s):  
Jun-Young Park ◽  
Abdul-Majeed Azad ◽  
Sun-Ju Song ◽  
Eric D. Wachsman

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