In recent years, photocatalytic technology has received attention for environmental protection. In this study, the usefulness of iron nanostructures generated by anodization was confirmed. Moreover, the synergistic effect of anodized iron (hematite, α-Fe₂O₃) and MWCNT (multi-walled carbon nanotube) was confirmed by methylene blue (MB) decomposition by MWCNT /α-Fe₂O₃ composite material. Electrophoretic deposition(EPD) was used as a method of making the MWCNT/α-Fe₂O₃ composite material. Characterization of the anodized samples and samples after EPD was performed by SEM and XRD, and concentration measurement of MB decomposition was performed using a spectrophotometer. The MB decomposition rate was improved in all the samples with MWCNT and the highest obtained with the MWCNT/α-Fe₂O₃ sample