Selective aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran catalyzed by Cu-based metal organic frameworks with 2,2,6,6-tetramethylpiperidin-oxyl

2019 ◽  
Vol 102 ◽  
pp. 242-249 ◽  
Author(s):  
Jia-Yin Lin ◽  
Min-Hao Yuan ◽  
Kun-Yi Andrew Lin ◽  
Chia-Hua Lin
Keyword(s):  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Selective Aerobic Oxidation

scholarly journals Cobalt-Based Metal Organic Frameworks as Solids Catalysts for Oxidation Reactions

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 95
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Eva Montero Lanzuela ◽  
Sergio Navalon ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Acid Sites ◽  
Crystalline Lattice ◽  
Oxidation Reactions ◽  
Solid Catalysts ◽  
Long Term Stability ◽  
Metal Organic

Metal organic frameworks (MOFs) are porous crystalline solids whose frameworks are constituted by metal ions/nodes with rigid organic linkers leading to the formation of materials having high surface area and pore volume. One of the unique features of MOFs is the presence of coordinatively unsaturated metal sites in their crystalline lattice that can act as Lewis acid sites promoting organic transformations, including aerobic oxidation reactions of various substrates such as hydrocarbons, alcohols, and sulfides. This review article summarizes the existing Co-based MOFs for oxidation reactions organized according to the nature of substrates like hydrocarbon, alcohol, olefin, and water. Both aerobic conditions and peroxide oxidants are discussed. Emphasis is placed on comparing the advantages of using MOFs as solid catalysts with respect to homogeneous salts in terms of product selectivity and long-term stability. The final section provides our view on future developments in this field.

Aerobic oxidation of thiols to disulfides using iron metal–organic frameworks as solid redox catalysts

2010 ◽  
Vol 46 (35) ◽  
pp. 6476 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Mercedes Alvaro ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Iron Metal ◽  
Redox Catalysts ◽  
Metal Organic

Cerium‐Based Metal–Organic Frameworks with UiO Architecture for Visible Light‐Induced Aerobic Oxidation of Benzyl Alcohol

Solar RRL ◽  
2019 ◽  
Vol 4 (8) ◽  
pp. 1900449 ◽  
Author(s):  
Xueying Qiu ◽  
Yanfei Zhu ◽  
Xiaofei Zhang ◽  
Yin Zhang ◽  
Leta Takele Menisa ◽  
...  
Keyword(s):  
Visible Light ◽  
Benzyl Alcohol ◽  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Oxidation Of Benzyl Alcohol ◽  
Metal Organic

Selective Aerobic Oxidation of a Metal–Organic Framework Boosts Thermodynamic and Kinetic Propylene/Propane Selectivity

2019 ◽  
Vol 131 (23) ◽  
pp. 7774-7778 ◽  
Author(s):  
Yu Wang ◽  
Ning‐Yu Huang ◽  
Xue‐Wen Zhang ◽  
Hai He ◽  
Rui‐Kang Huang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Metal Organic ◽  
Selective Aerobic Oxidation ◽  
Organic Framework
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