Aerobic oxidation of thiols to disulfides using iron metal–organic frameworks as solid redox catalysts

2010 ◽  
Vol 46 (35) ◽  
pp. 6476 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Mercedes Alvaro ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Iron Metal ◽  
Redox Catalysts ◽  
Metal Organic

ChemInform Abstract: Aerobic Oxidation of Thiols to Disulfides Using Iron Metal-Organic Frameworks as Solid Redox Catalysts.

ChemInform ◽  
2011 ◽  
Vol 42 (6) ◽  
pp. no-no
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Mercedes Alvaro ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Iron Metal ◽  
Redox Catalysts ◽  
Metal Organic

scholarly journals Cobalt-Based Metal Organic Frameworks as Solids Catalysts for Oxidation Reactions

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 95
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Eva Montero Lanzuela ◽  
Sergio Navalon ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Acid Sites ◽  
Crystalline Lattice ◽  
Oxidation Reactions ◽  
Solid Catalysts ◽  
Long Term Stability ◽  
Metal Organic

Metal organic frameworks (MOFs) are porous crystalline solids whose frameworks are constituted by metal ions/nodes with rigid organic linkers leading to the formation of materials having high surface area and pore volume. One of the unique features of MOFs is the presence of coordinatively unsaturated metal sites in their crystalline lattice that can act as Lewis acid sites promoting organic transformations, including aerobic oxidation reactions of various substrates such as hydrocarbons, alcohols, and sulfides. This review article summarizes the existing Co-based MOFs for oxidation reactions organized according to the nature of substrates like hydrocarbon, alcohol, olefin, and water. Both aerobic conditions and peroxide oxidants are discussed. Emphasis is placed on comparing the advantages of using MOFs as solid catalysts with respect to homogeneous salts in terms of product selectivity and long-term stability. The final section provides our view on future developments in this field.

Cerium-based UiO-66 metal–organic frameworks explored as efficient redox catalysts: titanium incorporation and generation of abundant oxygen vacancies

2019 ◽  
Vol 55 (93) ◽  
pp. 13959-13962 ◽  
Author(s):  
Yajun Zhang ◽  
Hanjiao Chen ◽  
Yi Pan ◽  
Xiaoliang Zeng ◽  
Xiaofang Jiang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Oxygen Vacancies ◽  
Metal Organic Frameworks ◽  
Redox Catalysts ◽  
Metal Organic ◽  
Titanium Incorporation ◽  
First Time

For the first time, UiO-66(Ce) was endowed with greatly improved redox photocatalytic activity via Ti incorporation, based on the formation of oxygen vacancies.

Cerium‐Based Metal–Organic Frameworks with UiO Architecture for Visible Light‐Induced Aerobic Oxidation of Benzyl Alcohol

Solar RRL ◽  
2019 ◽  
Vol 4 (8) ◽  
pp. 1900449 ◽  
Author(s):  
Xueying Qiu ◽  
Yanfei Zhu ◽  
Xiaofei Zhang ◽  
Yin Zhang ◽  
Leta Takele Menisa ◽  
...  
Keyword(s):  
Visible Light ◽  
Benzyl Alcohol ◽  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Oxidation Of Benzyl Alcohol ◽  
Metal Organic

scholarly journals Highly effective photoreduction of CO2 to CO promoted by integration of CdS with molecular redox catalysts through metal–organic frameworks

2018 ◽  
Vol 9 (47) ◽  
pp. 8890-8894 ◽  
Author(s):  
Chunjun Chen ◽  
Tianbin Wu ◽  
Haihong Wu ◽  
Huizhen Liu ◽  
Qingli Qian ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Redox Catalysts ◽  
Highly Effective ◽  
Metal Organic

CdS/UiO-bpy/Co composites showed outstanding performance for photoreduction of CO2 to CO via integrating CdS with a Co complex through MOFs.

Iron Metal-Organic Frameworks MIL-88B and NH2-MIL-88B for the Loading and Delivery of the Gasotransmitter Carbon Monoxide

2013 ◽  
Vol 19 (21) ◽  
pp. 6785-6790 ◽  
Author(s):  
Mingyan Ma ◽  
Heshmat Noei ◽  
Bernd Mienert ◽  
Johanna Niesel ◽  
Eckhard Bill ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Metal Organic Frameworks ◽  
Iron Metal ◽  
Metal Organic
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