scholarly journals Theoretical investigation of mechanism and ligand effects on half-sandwich iridium complexes for direct reductive amination

2022 ◽  
Vol 517 ◽  
pp. 112050
Author(s):  
Jingyi Wang ◽  
Chengyu Liu ◽  
Liming Cao ◽  
Yan Xiong ◽  
Jinxing Ye ◽  
...  
Keyword(s):  
Theoretical Investigation ◽  
Reductive Amination ◽  
Iridium Complexes ◽  
Ligand Effects ◽  
Half Sandwich

Half-sandwich ruthenium, rhodium and iridium complexes featuring oxime ligands: Structural studies and preliminary investigation of in vitro and in vivo anti-tumour activities

2016 ◽  
Vol 31 (7) ◽  
pp. e3640 ◽  
Author(s):  
Narasinga Rao Palepu ◽  
Sanjay Adhikari ◽  
Richard Premkumar J ◽  
Akalesh K. Verma ◽  
Samantha L. Shepherd ◽  
...  
Keyword(s):  
Preliminary Investigation ◽  
Iridium Complexes ◽  
Structural Studies ◽  
Half Sandwich

Half-sandwich iridium complexes—Synthesis and applications in catalysis

2008 ◽  
Vol 252 (5-7) ◽  
pp. 782-809 ◽  
Author(s):  
Jianke Liu ◽  
Xiaofeng Wu ◽  
Jon A. Iggo ◽  
Jianliang Xiao
Keyword(s):  
Iridium Complexes ◽  
Half Sandwich

The synthesis and reactivity of 16-electron half-sandwich iridium complexes bearing a carboranylthioamide ligand

2017 ◽  
Vol 46 (44) ◽  
pp. 15535-15540 ◽  
Author(s):  
Peng-Fei Cui ◽  
Yue-Jian Lin ◽  
Guo-Xin Jin
Keyword(s):  
Binuclear Complex ◽  
Donor Ligands ◽  
Iridium Complexes ◽  
Insertion Reactions ◽  
Metal Bond ◽  
Metal Metal ◽  
Half Sandwich

The 16-electron complex 2 has been synthesized. It can react with different donor ligands and undergoes M–S bond insertion reactions with DMAD. Complex 2 is shown to react with [Cp*Ir] unit to form a M–M-bound binuclear complex. Interestingly, the metal–metal bond could be broken by HCl to produce the selective B(6)–H activation species.

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