Influences of micropores and water molecules in the palygorskite structure on the color and stability of Maya blue pigment

Author(s):  
Guanzheng Zhuang ◽  
Li Li ◽  
Mengyuan Li ◽  
Peng Yuan
Author(s):  
Manuel Sánchez del Río ◽  
Antonio Doménech ◽  
María Teresa Doménech-Carbó ◽  
María Luisa Vázquez de Agredos Pascual ◽  
Mercedes Suárez ◽  
...  
Keyword(s):  

1962 ◽  
Vol 27 (4) ◽  
pp. 557-564 ◽  
Author(s):  
Rutherford J. Gettens

AbstractThe early peoples of Southern Mexico decorated pottery and painted pictures on walls with a stable blue pigment which is not found elsewhere in the world. Investigation of this blue was started over 30 years ago, but still the true nature of the blue color principle is unknown. Since the blue cannot be destroyed by boiling nitric acid, it does not seem to be vegetable or organic in origin. It is quite unlike azurite or natural ultramarine or other blue minerals which were employed as sources of blue pigment by other ancient peoples. The main obstacle in the investigation is the extreme scarcity of research material. The only samples of the blue available for testing are thinly painted films on potsherds and on wall painting fragments where it is mixed with lime plaster and other impurities. Although attempts to procure lump specimens of the blue, even in gram quantitives, have failed, some progress has been made. It is now known that the inorganic base of the blue pigment is a clay mineral called attapulgite. Ordinary attapulgite is nearly colorless. We still do not know what makes the clay blue; whether it is a special kind of attapulgite or if the Maya produced it artifically. In this paper all the evidence accumulated to date is reviewed.


2011 ◽  
Vol 12 (2) ◽  
pp. 140-148 ◽  
Author(s):  
María Luisa Vázquez de Ágredos Pascual ◽  
María Teresa Doménech Carbó ◽  
Antonio Doménech Carbó

2012 ◽  
Vol 1374 ◽  
pp. 115-123
Author(s):  
Silvia Fernández-Sabido ◽  
Yoly Palomo-Carrillo ◽  
Rafael Burgos-Villanueva ◽  
Romeo de Coss

ABSTRACTA comparative study of two blue pigment found in separate megalithic structures in Yucatán México is presented. The first sample (M1) is a piece of turquoise stucco discovered at the top of a building known as Structure-2 in the town of Dzilam González. The second sample (M2) is a residual blue powder that was contained in a Oxcum Café type ceramic vessel recovered in the rubble of the Kabul building in Izamal city. The interest in characterizing these samples increases with the possibility of finding in them evidence of Maya Blue, a dye created in the eighth century by the Maya people, whose extraordinary physical and chemical properties have been studied in laboratories around the world. Maya Blue was a tailored technology used for several centuries, even during the Spanish occupation, throughout Mesoamerica. Despite 80 years of study, the mysteries of its composition, traditional preparation and obsolescence have not yet been fully resolved. Using different spectroscopic techniques (SEM, EDX, XRD, FTIR, UV-Vis DR) we have studied and compared the blue colorants in M1 and M2. Results indicate that M1 is Maya Blue. Despite some similarities in the infrarred vibrational spectra of the two samples, we have determinated that M2 is not Maya Blue but a non-Mesoamerican mineral pigment known as Ultramarine which was probably introduced to America by Europeans.


Author(s):  
M. Sánchez del Río ◽  
A. Sodo ◽  
S.G. Eeckhout ◽  
T. Neisius ◽  
P. Martinetto ◽  
...  
Keyword(s):  

Archaeometry ◽  
2006 ◽  
Vol 48 (1) ◽  
pp. 115-130 ◽  
Author(s):  
M. SÁNCHEZ DEL RÍO ◽  
P. MARTINETTO ◽  
C. REYES-VALERIO ◽  
E. DOORYHÉE ◽  
M. SUÁREZ

2004 ◽  
Vol 59 (10-11) ◽  
pp. 1619-1625 ◽  
Author(s):  
M. Sánchez del Río ◽  
P. Martinetto ◽  
A. Somogyi ◽  
C. Reyes-Valerio ◽  
E. Dooryhée ◽  
...  
Keyword(s):  

2005 ◽  
Vol 16 (1) ◽  
pp. 51-62 ◽  
Author(s):  
Dean E. Arnold

Maya Blue is an unusual blue pigment used on pottery, sculpture, and murals from the Preclassic to the Colonial period. Until the late 1960s, its composition was unknown, but chemists working in Spain, Belgium, Mexico, and the United States identified Maya Blue as a combination of indigo and the unusual clay mineral palygorskite (also called attapulgite). A source of palygorskite in the Maya area was unknown for years; then ethnoarchaeological research in the mid-1960s demonstrated that the contemporary Maya recognized the unique physical properties of palygorskite and used it as an additive for pottery temper and for curing certain types of illnesses. Because of its importance in Maya Blue, pre-Hispanic sources of the mineral were then suggested based on ethnoarchaeological data. One of these sources was the cenote in the town of Sacalum, Yucatan. This paper briefly reviews the history of the Maya Blue research from an anthropological perspective and presents evidence of a second possible pre-Hispanic mining site for palygorskite at Yo' Sah Kab near Ticul, Yucatan. Archaeological and technological approaches have demonstrated the use, distribution, composition, and characteristics of Maya Blue, but ethnoarchaeology has related it to Maya language and culture and to possible pre-Hispanic sources of one of its constituents, palygorskite.


Sign in / Sign up

Export Citation Format

Share Document