Selective oxidation of glucose to glucuronic acid by cesium-promoted gold nanoparticle catalyst

2016 ◽  
Vol 422 ◽  
pp. 35-42 ◽  
Author(s):  
Robert Wojcieszak ◽  
Iolanda M. Cuccovia ◽  
Márcia A. Silva ◽  
Liane M. Rossi
2009 ◽  
pp. 5302 ◽  
Author(s):  
Takato Mitsudome ◽  
Akifumi Noujima ◽  
Tomoo Mizugaki ◽  
Koichiro Jitsukawa ◽  
Kiyotomi Kaneda

ChemInform ◽  
2010 ◽  
Vol 41 (3) ◽  
Author(s):  
Takato Mitsudome ◽  
Akifumi Noujima ◽  
Tomoo Mizugaki ◽  
Koichiro Jitsukawa ◽  
Kiyotomi Kaneda

Author(s):  
Sebastian Franz ◽  
Nataliya D. Shcherban ◽  
Igor Bezverkhyy ◽  
Sergii A. Sergiienko ◽  
Irina L. Simakova ◽  
...  

AbstractOxidation of a mixture of glucose and arabinose over Au particles deposited on porous carbons, N-doped carbons and carbon nitrides was investigated at 70 °C, under constant pH of 8, and oxygen partial pressure 0.125 atm. In particular, Au deposited on nitrogen-containing carbon-based mesoporous structures demonstrated activity in the oxidation of the sugars to the corresponding aldonic acids higher than gold deposited on undoped carbon supports (conversion of glucose up to ca. 60%, arabinose–ca. 30% after 200 min). The results can be explained by the basic nature of the supports leading to an increase in the polarity of the carbon surface and the oxygen activation. Glucuronic acid (with selectivity ca. 10–93.5%) together with gluconic acid was formed as a result of glucose oxidation, while arabinose was selectively oxidized to arabinonic acid.


2013 ◽  
Vol 19 (43) ◽  
pp. 14398-14402 ◽  
Author(s):  
Takato Mitsudome ◽  
Yuya Yamamoto ◽  
Akifumi Noujima ◽  
Tomoo Mizugaki ◽  
Koichiro Jitsukawa ◽  
...  

Author(s):  
Xing-Yue Qi ◽  
Yalin He ◽  
Yan Yao ◽  
Lu Zhang ◽  
Yiran Li ◽  
...  

Catalytic selective oxidation of glucose into value-added gluconic acid is one of the sustainable routes for biomass utilization, for which the supported Au catalysts have been widely explored. Au/CeO2 was...


2013 ◽  
Vol 19 (S2) ◽  
pp. 1708-1709
Author(s):  
T. Tanaka ◽  
N. Yamamoto ◽  
T. Kunio

Extended abstract of a paper presented at Microscopy and Microanalysis 2013 in Indianapolis, Indiana, USA, August 4 – August 8, 2013.


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